Crystal chemistry and selected physical properties of inorganic fluorides and oxide-fluorides

M Leblanc, V Maisonneuve, A Tressaud - Chemical reviews, 2015 - ACS Publications
1.1. Interest of Inorganic Metal Fluorides Inorganic metal fluorides and oxide-fluorides have
significant importance in the development of many new technologies, and are impacting …

Optical properties and luminescence behavior of Tb3+-Doped SiO2–Al2O3–BaO–BaF2 oxyfluoride glasses and glass ceramics

L Farahinia, M Rezvani, AA Kordlar - Ceramics International, 2024 - Elsevier
In this study, oxyfluoride glasses with chemical composition of 45SiO 2–15Al 2 O 3–10BaO–
30BaF 2-xTbF 3 (x= 0.2, 0.4 and 0.6 (mole ratios)) were prepared through the conventional …

Network structure and rare-earth ion local environments in fluoride phosphate photonic glasses studied by solid-state NMR and electron paramagnetic resonance …

M de Oliveira Jr, T Uesbeck, TS Goncalves… - The Journal of …, 2015 - ACS Publications
A detailed structural investigation of a series of fluoride phosphate laser glasses with
nominal composition 25BaF2–25SrF2–(30–x) Al (PO3) 3–x AlF3–(20–z) YF3: z REF3 with …

Intense 2.8 μm emission of Ho3+ doped PbF2 single crystal

P Zhang, J Yin, B Zhang, L Zhang, J Hong, J He… - Optics letters, 2014 - opg.optica.org
A Ho^ 3+-doped PbF_2 mid-IR laser crystal was successfully grown using the vertical
Bridgman method. An intense 2.8 μm emission in Ho: PbF_2 crystal was observed for the …

Sensitization and deactivation effects of Nd3+on the Ho3+ : 3.9 μm emission in a PbF2 crystal

P Zhang, Y Hang, Z Li, Z Chen, H Yin, S Zhu, S Fu… - Optics Letters, 2017 - opg.optica.org
The use of Nd^ 3+ codo** for sensitizing the Ho^ 3+ ion and enhancing the∼ 3.9 μm
emission from Ho^ 3+: I_55→ I_65 was investigated in the PbF_2 crystal for the first time, to …

Composition–structure–property correlations in rare-earth-doped heavy metal oxyfluoride glasses

C Doerenkamp, E Carvajal, CJ Magon… - The Journal of …, 2019 - ACS Publications
Structure–property correlations in oxyfluoride glasses have been explored in a series of lead
fluoroborate and lead fluorogermanate glasses with nominal compositions (50–x–y–z) B2O3 …

Mixed valence effects in Pr: YbF3 nanocrystals and influence to EPR, magnetic and Faraday rotation properties of diamagnetic glasses

X Zhang, Q Chen, S Zhang - Journal of Non-Crystalline Solids, 2021 - Elsevier
The co-existence of light and heavy rare earth ions will arouse interesting optical, magnetic
and magneto optical properties to matrix due to energy transfer between various rare earth …

NMR and ESR relaxation in Nd-and Gd-doped LaPO 4: towards the accurate determination of the do** concentration

S Maron, G Dantelle, T Gacoin… - Physical Chemistry …, 2014 - pubs.rsc.org
We present an original method based on the 31P solid-state NMR relaxation to determine
low concentrations (< 1 at%) of paramagnetic ions in monazite LaPO4 crystals with a high …

Enhanced emission of 2.86 μm from diode-pumped Ho3+/Yb3+-codoped PbF2 crystal

P Zhang, B Zhang, J Hong, L Zhang, J He, Y Hang - Optics express, 2015 - opg.optica.org
A novel Ho^ 3+/Yb^ 3+-codoped PbF_2 mid-IR laser crystal was successfully grown and
analyzed. Enhanced emission at 2.86 μm was observed from the crystal under excitation of …

Infrared and cooperative luminescence in Yb3+ doped calcium aluminate CaAl4O7

M Puchalska, M Sobczyk, J Targowska, A Watras… - Journal of …, 2013 - Elsevier
Two series of calcium aluminates: Singly doped CaAl 4 O 7: Yb (x%) and co-doped CaAl 4 O
7: Yb (x%), Na (x%)(x= 0.002, 0.01, 0.02, 0.04, 0.05, 0.06, 0.07, 0.1) were synthesized by a …