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Second and outer coordination sphere effects in nitrogenase, hydrogenase, formate dehydrogenase, and CO dehydrogenase
Gases like H2, N2, CO2, and CO are increasingly recognized as critical feedstock in “green”
energy conversion and as sources of nitrogen and carbon for the agricultural and chemical …
energy conversion and as sources of nitrogen and carbon for the agricultural and chemical …
Biological hydrogen with industrial potential: Improvement and prospection in biohydrogen production
W Chen, T Li, Y Ren, J Wang, H Chen… - Journal of Cleaner …, 2023 - Elsevier
Hydrogen is an important industrial material and ideal secondary energy. It is widely used in
petrochemical, electronics, metallurgy, food processing, fine organic synthesis, and clean …
petrochemical, electronics, metallurgy, food processing, fine organic synthesis, and clean …
Minimal and hybrid hydrogenases are active from archaea
Microbial hydrogen (H 2) cycling underpins the diversity and functionality of diverse anoxic
ecosystems. Among the three evolutionarily distinct hydrogenase superfamilies …
ecosystems. Among the three evolutionarily distinct hydrogenase superfamilies …
The catalytic cycle of [FeFe] hydrogenase: A tale of two sites
Ever since the discovery of hydrogenases over 90 years ago (Stephenson and Stickland,
1931), their structure and mechanism of action have been intensively investigated. Of the …
1931), their structure and mechanism of action have been intensively investigated. Of the …
Current state of [FeFe]-hydrogenase research: biodiversity and spectroscopic investigations
Hydrogenases are redox enzymes that catalyze the conversion of protons and molecular
hydrogen (H2). Based on the composition of the active site cofactor, the monometallic [Fe] …
hydrogen (H2). Based on the composition of the active site cofactor, the monometallic [Fe] …
[HTML][HTML] Nanomaterial-biological hybrid systems: Advancements in solar-driven CO2-to-chemical conversion
The nanomaterial-biological hybrid system (NBHS) is a rapidly growing interdisciplinary field
that combines photocatalytic nanomaterials with biological systems, leveraging the superior …
that combines photocatalytic nanomaterials with biological systems, leveraging the superior …
Genetic engineering contribution to develo** cyanobacteria-based hydrogen energy to reduce carbon emissions and establish a hydrogen economy
GK Kamshybayeva, BD Kossalbayev… - International Journal of …, 2024 - Elsevier
Growing concerns over greenhouse gas emissions and energy insecurity caused by the
depletion of conventional fuels have led to a search for sustainable fuel alternatives. As an …
depletion of conventional fuels have led to a search for sustainable fuel alternatives. As an …
Photocatalyst-enzyme hybrid systems for light-driven biotransformation
N Yang, Y Tian, M Zhang, X Peng, F Li, J Li, Y Li… - Biotechnology …, 2022 - Elsevier
Enzymes catalyse target reactions under mild conditions with high efficiency, as well as
excellent regional-, stereo-, and enantiomeric selectivity. Photocatalysis utilises sustainable …
excellent regional-, stereo-, and enantiomeric selectivity. Photocatalysis utilises sustainable …
Proton transfer mechanisms in bimetallic hydrogenases
H Tai, S Hirota, ST Stripp - Accounts of Chemical Research, 2020 - ACS Publications
Conspectus Hydrogenases are metalloenzymes that catalyze proton reduction and H2
oxidation with outstanding efficiency. They are model systems for bioinorganic chemistry …
oxidation with outstanding efficiency. They are model systems for bioinorganic chemistry …
Photosynthetic hydrogen production: Novel protocols, promising engineering approaches and application of semi‐synthetic hydrogenases
Photosynthetic production of molecular hydrogen (H2) by cyanobacteria and green algae is
a potential source of renewable energy. These organisms are capable of water …
a potential source of renewable energy. These organisms are capable of water …