Model studies of heterogeneous catalytic hydrogenation reactions with gold

M Pan, AJ Brush, ZD Pozun, HC Ham, WY Yu… - Chemical Society …, 2013 - pubs.rsc.org
Supported gold nanoparticles have recently been shown to possess intriguing catalytic
activity for hydrogenation reactions, particularly for selective hydrogenation reactions …

Catalytic Reductive Alcohol Etherifications with Carbonyl‐Based Compounds or CO2 and Related Transformations for the Synthesis of Ether Derivatives

C Lluna‐Galán, L Izquierdo‐Aranda, R Adam… - …, 2021 - Wiley Online Library
Ether derivatives have myriad applications in several areas of chemical industry and
academia. Hence, the development of more effective and sustainable protocols for their …

Hydrogen adsorption and absorption with Pd–Au bimetallic surfaces

WY Yu, GM Mullen, CB Mullins - The Journal of Physical …, 2013 - ACS Publications
Pd–Au bimetallic catalysts have shown promising performance in numerous reactions that
involve hydrogen. Fundamental studies of hydrogen interactions with Pd–Au surfaces could …

Tandem Denitrogenation Oxidative Coupling Reaction of Phenyl Vinyl Azides and Cyclic Ethers Under Metal‐Free Conditions

D Mou, Q Li, Z Du - ChemistrySelect, 2023 - Wiley Online Library
An efficient synthesis of α‐oxoalkyl ketones is described. The current method is the coupling
reaction of phenyl vinyl azides and cyclic ethers under metal‐free conditions. The reaction is …

Design and preparation of supported Au catalyst with enhanced catalytic activities by rationally positioning Au nanoparticles on anatase

L Wang, H Wang, AE Rice, W Zhang, X Li… - The Journal of …, 2015 - ACS Publications
A synergistic effect between individual components is crucial for increasing the activity of
metal/metal oxide catalysts. The greatest challenge is how to control the synergistic effect to …

Model studies with gold: a versatile oxidation and hydrogenation catalyst

M Pan, J Gong, G Dong, CB Mullins - Accounts of Chemical …, 2014 - ACS Publications
Historically, scientists have considered gold an inert catalyst constituent. However, in recent
decades, chemists have discovered that nanoscale gold shows exceptional activity for many …

Application of thiolate self-assembled monolayers in selective alcohol oxidation for suppression of Pd catalyst deactivation

P Hao, S Pylypenko, DK Schwartz, JW Medlin - Journal of Catalysis, 2016 - Elsevier
Rapid deactivation often reduces the effectiveness of Pt-group catalysts in the low-
temperature aerobic oxidation of alcohols. Here, we report the use of thiolate self-assembled …

Nickel-Catalyzed Reductive Etherification of Aldehydes at Room Temperature: C–O vs C–C Bond Formation

S Rahimi, F Panahi, M Bahmani… - The Journal of Organic …, 2018 - ACS Publications
The reaction of secondary and tertiary benzyl alcohols activated by 2, 4, 6-trichloro-1, 3, 5-
triazine (TCT) with aldehydes in the presence of NiCl2· dmg as a precatalyst in ethylene …

Methanol O–H bond dissociation on H-precovered gold originating from a structure with a wide range of surface stability

AJ Brush, M Pan, CB Mullins - The Journal of Physical Chemistry …, 2012 - ACS Publications
Gold has been shown to exhibit promising catalytic activity, and understanding the
fundamental interactions of reactants and hydrogen atoms on a gold surface is key to …

[PDF][PDF] Modifying Supported Palladium Catalysts Using Self-Assembled Monolayers for Liquid-Phase Reactions

P Hao - 2018 - scholar.colorado.edu
Since the earliest times when fermentation was used to produce alcohol, catalysis has been
develo** with human civilization [1]. Many catalytic processes have carried production …