The appearance of ferrocene in the middle of the 20th century has revolutionized
organometallic chemistry and is now providing applications in areas as varied and …

The interest in chiral tricoordinated sulfur compounds in general, and sulfoxides in
particular, has shifted from purely academic, directed toward the study of their …

Despite the impressive progress achieved in asymmetric catalysis during the last decade, an
increasing number of new catalysts, ligands, and applications are reported every year to …

Planar-chiral ferrocenes are widely applied in catalytic asymmetric transformations in
scientific research as well as in industry. A plethora of different methodologies have been …

Chirally modified vanadium complexes have been used as catalysts in enantioselective
epoxidations of allylic alcohols and asymmetric sulfide to sulfoxide oxidations. For both …

The construction of carbon-carbon and carbonheteroatom bonds by transition-metal-
mediated organic processes has become fundamental to the science of synthetic organic …

A novel class of planar chiral electron-rich monophosphine ligands has been developed.
The modular design allows a short and efficient synthesis of an array of aryl-ferrocenyl …

Planar chiral monodentate 1, 3-disubstituted ferrocene phosphines inspired on JohnPhos-
type ligands have been synthesized and applied to the enantioselective gold (I) catalyzed …

One of the most powerful approaches for the formation of simple and complex chiral
molecules is the metal-catalysed asymmetric allylic alkylation. This reaction has been …

[2.2] Paracyclophane is a fascinating molecule that offers great potential in a wide range of
chemical disciplines. Currently, the synthesis of the majority of enantiomerically pure [2.2] …