Recent advances in catalysis involving bidentate N-heterocyclic carbene ligands
Since the discovery of persistent carbenes by the isolation of 1, 3-di-l-adamantylimidazol-2-
ylidene by Arduengo and coworkers, we witnessed a fast growth in the design and …
ylidene by Arduengo and coworkers, we witnessed a fast growth in the design and …
N-heterocyclic carbenes as bridgehead donors in metal pincer complexes
Rigid terdentate 'pincer'ligands containing a bridgehead N-heterocyclic carbene (NHC)
donor attract considerable interest as spectators in transition metal complexes with broad …
donor attract considerable interest as spectators in transition metal complexes with broad …
Cobalt (III) Complexes of Pyridine-Functionalized Chelating NHC Ligands: Effective Catalysts for the Olefination of Alcohols Using Sulfones
Several air-stable cobalt (III) complexes 1a-d featuring pyridine-functionalized NHC ligand
systems were synthesized and completely characterized. These complexes were then …
systems were synthesized and completely characterized. These complexes were then …
The Importance of kinetic and thermodynamic control when assessing mechanisms of carboxylate-assisted C–H Activation
The reactions of substituted 1-phenylpyrazoles (phpyz-H) at [MCl2Cp*] 2 dimers (M= Rh, Ir;
Cp*= C5Me5) in the presence of NaOAc to form cyclometalated Cp* M (phpyz) Cl were …
Cp*= C5Me5) in the presence of NaOAc to form cyclometalated Cp* M (phpyz) Cl were …
Effect of ancillary ligand in cyclometalated Ru (II)–NHC-catalyzed transfer hydrogenation of unsaturated compounds
In an effort to develop efficient Ru (II)–NHC-based catalyst considering their stereoelectronic
effect for hydride-transfer reaction, we found that the ancillary NHC ligand can play a …
effect for hydride-transfer reaction, we found that the ancillary NHC ligand can play a …
Experimental and Computational Studies on the Acetate-Assisted C–H Activation of N-Aryl Imidazolium Salts at Rhodium and Iridium: A Chloride Additive Changes …
N Tamosiunaite, LC Logie, SE Neale… - The Journal of …, 2021 - ACS Publications
Combined experimental and computational mechanistic studies of the reactions of
unsymmetrical, para-substituted N-aryl imidazolium salts, L2-R 1, R 2, at [MCl2Cp*] 2 (M …
unsymmetrical, para-substituted N-aryl imidazolium salts, L2-R 1, R 2, at [MCl2Cp*] 2 (M …
Ruthenacycles and iridacycles as transfer hydrogenation catalysts
In this review, we describe the synthesis and use in hydrogen transfer reactions of
ruthenacycles and iridacycles. The review limits itself to metallacycles where a ligand is …
ruthenacycles and iridacycles. The review limits itself to metallacycles where a ligand is …
Reduction of carbon dioxide with ammonia-borane under ambient conditions: maneuvering a catalytic way
In the development of alternatives to the traditional catalytic hydrogenation of CO2 with
gaseous H2, employing nongaseous H2 storage compounds as potential reductants for …
gaseous H2, employing nongaseous H2 storage compounds as potential reductants for …
Multidentate NHC complexes of group IX metals featuring carbon-based tethers: Synthesis and applications
Incorporation of N-tethers to N-heterocyclic carbene ligands to form a powerful class of
multidentate, responsive ligand frameworks that have proven to be more than just ancillary …
multidentate, responsive ligand frameworks that have proven to be more than just ancillary …
Heteroditopic Ru (II)–and Ir (III)–NHC complexes with pendant 1, 2, 3-triazole/triazolylidene groups: stereoelectronic impact on transfer hydrogenation of unsaturated …
Imidazol-2-ylidene (ImNHC) and 1, 2, 3-traizol-5-ylidene (tzNHC) have been established as
important classes of carbene ligands in homogeneous catalysis. To develop Ru (II)/Ir (III) …
important classes of carbene ligands in homogeneous catalysis. To develop Ru (II)/Ir (III) …