Improving f-element single molecule magnets
ST Liddle, J van Slageren - Chemical Society Reviews, 2015 - pubs.rsc.org
Ever since the discovery that certain manganese clusters retain their magnetisation for
months at low temperatures, there has been intense interest in molecular nanomagnets …
months at low temperatures, there has been intense interest in molecular nanomagnets …
Molecular magnetism of lanthanide: Advances and perspectives
Z Zhu, M Guo, XL Li, J Tang - Coordination Chemistry Reviews, 2019 - Elsevier
The discovery of the first example of lanthanide-based single molecule magnets (Ln-SMMs),
a revolutionary progress, marked the beginning of a new age for SMMs, has greatly inspired …
a revolutionary progress, marked the beginning of a new age for SMMs, has greatly inspired …
Ultrahard magnetism from mixed-valence dilanthanide complexes with metal-metal bonding
Metal-metal bonding interactions can engender outstanding magnetic properties in bulk
materials and molecules, and examples abound for the transition metals. Extending this …
materials and molecules, and examples abound for the transition metals. Extending this …
Molcas 8: New capabilities for multiconfigurational quantum chemical calculations across the periodic table
In this report, we summarize and describe the recent unique updates and additions to the
Molcas quantum chemistry program suite as contained in release version 8. These updates …
Molcas quantum chemistry program suite as contained in release version 8. These updates …
On approaching the limit of molecular magnetic anisotropy: a near‐perfect pentagonal bipyramidal dysprosium (III) single‐molecule magnet
We report a monometallic dysprosium complex,[Dy (OtBu) 2 (py) 5][BPh4](5), that shows the
largest effective energy barrier to magnetic relaxation of Ueff= 1815 (1) K. The massive …
largest effective energy barrier to magnetic relaxation of Ueff= 1815 (1) K. The massive …
High-temperature magnetic blocking and magneto-structural correlations in a series of dysprosium (III) metallocenium single-molecule magnets
KR McClain, CA Gould, K Chakarawet, SJ Teat… - Chemical …, 2018 - pubs.rsc.org
A series of dysprosium (III) metallocenium salts,[Dy (CpiPr4R) 2][B (C6F5) 4](R= H (1), Me
(2), Et (3), iPr (4)), was synthesized by reaction of DyI3 with the corresponding known …
(2), Et (3), iPr (4)), was synthesized by reaction of DyI3 with the corresponding known …
The rise of 3-d single-ion magnets in molecular magnetism: towards materials from molecules?
Single-molecule magnets (SMMs) that contain one spin centre (so-called single-ion
magnets) theoretically represent the smallest possible unit for spin-based electronic devices …
magnets) theoretically represent the smallest possible unit for spin-based electronic devices …
An air-stable Dy (III) single-ion magnet with high anisotropy barrier and blocking temperature
Herein we report air-stable Dy (III) and Er (III) single-ion magnets (SIMs) with pseudo-D5h
symmetry, synthesized from a sterically encumbered phosphonamide, tBuPO (NHiPr) 2 …
symmetry, synthesized from a sterically encumbered phosphonamide, tBuPO (NHiPr) 2 …
Molecular magnetism
NF Chilton - Annual Review of Materials Research, 2022 - annualreviews.org
Molecular magnetism, though distinctly a field within chemistry, encompasses much more
than synthesis and has strong links with other disciplines across the physical sciences …
than synthesis and has strong links with other disciplines across the physical sciences …
Emerging trends on designing high-performance dysprosium (III) single-molecule magnets
TG Ashebr, H Li, X Ying, XL Li, C Zhao, S Liu… - ACS Materials …, 2022 - ACS Publications
The present prospect of single-molecule magnets (SMMs) research is more appealing after
the detection of magnetic remanence above liquid-nitrogen temperatures. From the current …
the detection of magnetic remanence above liquid-nitrogen temperatures. From the current …