Earth-abundant heterogeneous water oxidation catalysts
Water oxidation is a key chemical transformation for the conversion of solar energy into
chemical fuels. Our review focuses on recent work on robust earth-abundant heterogeneous …
chemical fuels. Our review focuses on recent work on robust earth-abundant heterogeneous …
Design of molecular water oxidation catalysts with earth-abundant metal ions
M Kondo, H Tatewaki, S Masaoka - Chemical Society Reviews, 2021 - pubs.rsc.org
The four-electron oxidation of water (2H2O→ O2+ 4H++ 4e−) is considered the main
bottleneck in artificial photosynthesis. In nature, this reaction is catalysed by a Mn4CaO5 …
bottleneck in artificial photosynthesis. In nature, this reaction is catalysed by a Mn4CaO5 …
Design and optimization of catalysts based on mechanistic insights derived from quantum chemical reaction modeling
Until recently, computational tools were mainly used to explain chemical reactions after
experimental results were obtained. With the rapid development of software and hardware …
experimental results were obtained. With the rapid development of software and hardware …
Water oxidation using earth-abundant transition metal catalysts: opportunities and challenges
Catalysts for the oxidation of H2O are an integral component of solar energy to fuel
conversion technologies. Although catalysts based on scarce and precious metals have …
conversion technologies. Although catalysts based on scarce and precious metals have …
Synthesis and reactivity of a mononuclear non-haem cobalt (IV)-oxo complex
Abstract Terminal cobalt (IV)–oxo (CoIV–O) species have been implicated as key
intermediates in various cobalt-mediated oxidation reactions. Herein we report the …
intermediates in various cobalt-mediated oxidation reactions. Herein we report the …
Heterogeneous electrocatalyst with molecular cobalt ions serving as the center of active sites
Molecular Co2+ ions were grafted onto doped graphene in a coordination environment,
resulting in the formation of molecularly well-defined, highly active electrocatalytic sites at a …
resulting in the formation of molecularly well-defined, highly active electrocatalytic sites at a …
Tuning the electronic properties of prussian blue analogues for efficient water oxidation electrocatalysis: Experimental and computational studies
Abstract Although several Prussian Blue analogues (PBAs) have been investigated as water
oxidation catalysts, the field lacks a comprehensive study that focuses on the design of the …
oxidation catalysts, the field lacks a comprehensive study that focuses on the design of the …
Selective oxidation of emerging organic contaminants in heterogeneous Fenton-like systems
Heterogeneous Fenton-like reaction shows great potential for eliminating organic
substances (eg emerging organic contaminants (EOCs)) in water, which has been widely …
substances (eg emerging organic contaminants (EOCs)) in water, which has been widely …
{Co4O4} and {CoxNi4–xO4} Cubane Water Oxidation Catalysts as Surface Cut-Outs of Cobalt Oxides
The future of artificial photosynthesis depends on economic and robust water oxidation
catalysts (WOCs). Cobalt-based WOCs are especially promising for knowledge transfer …
catalysts (WOCs). Cobalt-based WOCs are especially promising for knowledge transfer …
Accounting for the dynamic oxidative behavior of nickel anodes
The dynamic behavior of the anodic peak for amorphous nickel oxy/hydroxide (a-NiO x) films
in basic media was investigated. Chronocoulometry of films with known nickel …
in basic media was investigated. Chronocoulometry of films with known nickel …