Quantum tunneling of magnetization and related phenomena in molecular materials
D Gatteschi, R Sessoli - Angewandte Chemie International …, 2003 - Wiley Online Library
Molecules comprising a large number of coupled paramagnetic centers are attracting much
interest because they may show properties which are intermediate between those of simple …
interest because they may show properties which are intermediate between those of simple …
Filling the gap between the quantum and classical worlds of nanoscale magnetism: giant molecular aggregates based on paramagnetic 3d metal ions
In this review, aspects of the syntheses, structures and magnetic properties of giant 3d and
3d/4f paramagnetic metal clusters in moderate oxidation states are discussed. The term …
3d/4f paramagnetic metal clusters in moderate oxidation states are discussed. The term …
Quantentunneln der Magnetisierung und verwandte Phänomene in molekularen Materialien
D Gatteschi, R Sessoli - Angewandte Chemie, 2003 - Wiley Online Library
Moleküle mit einer großen Zahl gekoppelter paramagnetischer Zentren werden gegenwärtig
intensiv erforscht. Man hofft auf Eigenschaften zu treffen, die zwischen denen isolierter …
intensiv erforscht. Man hofft auf Eigenschaften zu treffen, die zwischen denen isolierter …
Molecular Engineering for Single‐Chain‐Magnet Behavior in a One‐Dimensional Dysprosium–Nitronyl Nitroxide Compound
The discovery of single molecule magnets (SMMs), about a decade ago,[1] opened up a
very lively scientific area where still both physicists and chemists join their efforts to better …
very lively scientific area where still both physicists and chemists join their efforts to better …
Magnetic qubits as hardware for quantum computers
We propose two potential realizations for quantum bits based on nanometre-scale magnetic
particles of large spin S and high-anisotropy molecular clusters. In case (1) the bit-value …
particles of large spin S and high-anisotropy molecular clusters. In case (1) the bit-value …
High-frequency EPR spectra of a molecular nanomagnet: Understanding quantum tunneling of the magnetization
AL Barra, D Gatteschi, R Sessoli - Physical Review B, 1997 - APS
EPR spectra have been recorded in very high fields up to 25 T, and at high frequency up to
525 GHz, on a polycrystalline sample of [Mn 12 O 12 (CH 3 COO) 16 (H 2 O) 4]⋅ 2 CH 3 …
525 GHz, on a polycrystalline sample of [Mn 12 O 12 (CH 3 COO) 16 (H 2 O) 4]⋅ 2 CH 3 …
Neutron spectroscopy for the magnetic anisotropy of molecular clusters
Neutron spectroscopy has been used to observe transitions between the energy levels for
the 21 different orientations of the S= 10 spin ground state of an octanuclear iron molecular …
the 21 different orientations of the S= 10 spin ground state of an octanuclear iron molecular …
Heterometallic 3d–4f single molecule magnets containing diamagnetic metal ions
Molecular nano magnets such as single-molecule magnets (SMMs) are a class of
coordination complexes with numerous potential applications such as information storage …
coordination complexes with numerous potential applications such as information storage …
Evidence for resonant tunneling of magnetization in sacetate complex
We have measured the dc magnetization at low temperatures of tetragonal crystals of Mn 12
acetate complex [Mn 12 O 12 (CH 3 COO) 16 (H 2 O) 4], a material composed of a large …
acetate complex [Mn 12 O 12 (CH 3 COO) 16 (H 2 O) 4], a material composed of a large …
EPR of molecular nanomagnets
Electron paramagnetic resonance has played a crucial role in the determination of the
properties and in explaining the origin of the peculiar behaviour of molecular nanomagnets …
properties and in explaining the origin of the peculiar behaviour of molecular nanomagnets …