Radical ligand-containing single-molecule magnets
Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …
and processing; however, such applications require large spin relaxation barriers and …
Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …
exchange and double exchange or spin crossover and valence tautomerism in small …
Valence tautomerism in metal complexes: Stimulated and reversible intramolecular electron transfer between metal centers and organic ligands
The defining characteristic of a valence tautomeric (VT) transition in a metal complex with a
redox-active organic ligand is a stimulated intramolecular electron transfer between metal …
redox-active organic ligand is a stimulated intramolecular electron transfer between metal …
Control of magnetic properties through external stimuli
O Sato, J Tao, YZ Zhang - Angewandte Chemie International …, 2007 - Wiley Online Library
The magnetic properties of many magnetic materials can be controlled by external stimuli.
The principal focus here is on the thermal, photochemical, electrochemical, and chemical …
The principal focus here is on the thermal, photochemical, electrochemical, and chemical …
Controlling dynamic magnetic properties of coordination clusters via switchable electronic configuration
W Huang, X Ma, O Sato, D Wu - Chemical Society Reviews, 2021 - pubs.rsc.org
Large-sized coordination clusters have emerged as a new class of molecular materials in
which many metal atoms and organic ligands are integrated to synergize their properties. As …
which many metal atoms and organic ligands are integrated to synergize their properties. As …
A 2D Semiquinone Radical-Containing Microporous Magnet with Solvent-Induced Switching from Tc = 26 to 80 K
The incorporation of tetraoxolene radical bridging ligands into a microporous magnetic solid
is demonstrated. Metalation of the redox-active bridging ligand 2, 5-dichloro-3, 6-dihydroxy …
is demonstrated. Metalation of the redox-active bridging ligand 2, 5-dichloro-3, 6-dihydroxy …
Quinonoid metal complexes: Toward molecular switches
The peculiar redox-active character of quinonoid metal complexes makes them extremely
appealing to design materials of potential technological interest. We show here how the …
appealing to design materials of potential technological interest. We show here how the …
Energy conversion and storage via photoinduced polarization change in non-ferroelectric molecular [CoGa] crystals
To alleviate the energy and environmental crisis, in the last decades, energy harvesting by
utilizing optical control has emerged as a promising solution. Here we report a polar crystal …
utilizing optical control has emerged as a promising solution. Here we report a polar crystal …
Spin crossover and valence tautomerism conductors
Multifunctional molecular materials exhibiting both magnetic bistability and electrical
conductivity have excellent application potential in microelectronic devices. In the last two …
conductivity have excellent application potential in microelectronic devices. In the last two …
Control of electronic polarization via charge ordering and electron transfer: electronic ferroelectrics and electronic pyroelectrics
Ferroelectric, pyroelectric, and piezoelectric compounds whose electric polarization
properties can be controlled by external stimuli such as electric field, temperature, and …
properties can be controlled by external stimuli such as electric field, temperature, and …