Metal stable isotope signatures as tracers in environmental geochemistry

JG Wiederhold - Environmental science & technology, 2015 - ACS Publications
The biogeochemical cycling of metals in natural systems is often accompanied by stable
isotope fractionation which can now be measured due to recent analytical advances. In …

Uranium isotope fractionation

MB Andersen, CH Stirling… - Reviews in Mineralogy …, 2017 - pubs.geoscienceworld.org
This review focuses on the rapidly growing field of natural 238U/235U variability, largely
driven by the technical advances in the measurement of U isotope ratios by mass …

Extensive marine anoxia during the terminal Ediacaran Period

F Zhang, S **ao, B Kendall, SJ Romaniello, H Cui… - Science …, 2018 - science.org
The terminal Ediacaran Period witnessed the decline of the Ediacara biota (which may have
included many stem-group animals). To test whether oceanic anoxia might have played a …

Mercury isotope fractionation during dark abiotic reduction of Hg (II) by dissolved, surface-bound, and structural Fe (II)

L Schwab, N Gallati, SM Reiter, RL Kimber… - Environmental …, 2023 - ACS Publications
Stable mercury (Hg) isotope ratios are an emerging tracer for biogeochemical
transformations in environmental systems, but their application requires knowledge of …

Mass fractionation laws, mass-independent effects, and isotopic anomalies

N Dauphas, EA Schauble - Annual Review of Earth and …, 2016 - annualreviews.org
Isotopic variations usually follow mass-dependent fractionation, meaning that the relative
variations in isotopic ratios scale with the difference in mass of the isotopes involved (eg …

Uranium isotopic compositions of the crust and ocean: Age corrections, U budget and global extent of modern anoxia

FLH Tissot, N Dauphas - Geochimica et Cosmochimica Acta, 2015 - Elsevier
The 238 U/235 U isotopic composition of uranium in seawater can provide important insights
into the modern U budget of the oceans. Using the double spike technique and a new data …

Uranium (IV) adsorption by natural organic matter in anoxic sediments

SE Bone, JJ Dynes, J Cliff… - Proceedings of the …, 2017 - National Acad Sciences
Uranium is an important carbon-free fuel source and environmental contaminant that
accumulates in the tetravalent state, U (IV), in anoxic sediments, such as ore deposits …

Uranium isotopes fingerprint biotic reduction

M Stylo, N Neubert, Y Wang, N Monga… - Proceedings of the …, 2015 - National Acad Sciences
Knowledge of paleo-redox conditions in the Earth's history provides a window into events
that shaped the evolution of life on our planet. The role of microbial activity in paleo-redox …

Electron flux is a key determinant of uranium isotope fractionation during bacterial reduction

AR Brown, M Molinas, Y Roebbert, A Sato… - … Earth & Environment, 2023 - nature.com
Uranium isotopic signatures in the rock record are utilized as a proxy for past redox
conditions on Earth. However, these signatures display significant variability that …

Uranium isotopes in marine carbonates as a global ocean paleoredox proxy: a critical review

F Zhang, TM Lenton, Á del Rey, SJ Romaniello… - … et Cosmochimica Acta, 2020 - Elsevier
The protracted oxygenation of the ocean-atmosphere system is one of the most fundamental
changes to the Earth system through its history. The uranium isotopic composition (238 …