Asymmetric synthesis of organophosphorus compounds using H–P reagents derived from chiral alcohols

JD Gbubele, TK Olszewski - Organic & Biomolecular Chemistry, 2021 - pubs.rsc.org
Chiral organophosphorus compounds, especially those containing C-stereogenic carbons
in the proximity of the phosphorus atom, are known for their unique properties and have …

Synthesis and Reactions of α-Hydroxyphosphonates

Z Rádai, G Keglevich - Molecules, 2018 - mdpi.com
This review summarizes the main synthetic routes towards α-hydroxyphosphonates that are
known as enzyme inhibitors, herbicides and antioxidants, moreover, a number of …

Asymmetric catalysis as a method for the synthesis of chiral organophosphorus compounds

OI Kolodiazhnyi, VP Kukhar, AO Kolodiazhna - Tetrahedron: Asymmetry, 2014 - Elsevier
This review discusses methods for the metallo-, organo-and biocatalytic asymmetric
synthesis of chiral organophosphorus compounds with many applications in stereoselective …

Catalytic Asymmetric Synthesis of C-Chiral Phosphonates

AO Kolodiazhna, OI Kolodiazhnyi - Symmetry, 2022 - mdpi.com
The current review is devoted to the achievements in the development of methods for the
catalytic asymmetric synthesis of phosphonates containing a chiral center in the side chain …

Organocatalytic enantioselective hydrophosphonylation of aldehydes

JV Alegre-Requena, E Marqués-López… - Organic & …, 2014 - pubs.rsc.org
We report our results concerning the first squaramide-catalysed hydrophosphonylation of
aldehydes. In all cases, the reactions proceeded smoothly and cleanly under mild reaction …

Stereoselective Syntheses of Organophosphorus Compounds

OI Kolodiazhnyi, AO Kolodiazhna - Symmetry, 2024 - mdpi.com
The review is devoted to the theoretical and synthetic aspects of the stereochemistry of
organophosphorus compounds. Organophosphorus compounds are not only widely exist in …

α-Hydroxyphosphonic acid derivatives of 2-azanorbornane: Synthesis, DFT calculations, and crystal structure analysis

TK Olszewski, E Wojaczyńska, R Wieczorek… - Tetrahedron …, 2015 - Elsevier
Highly diastereoselective hydrophosphonylation of 2-azanorbornane aldehyde exo-1 with
silylated phosphorus esters yielded the (S)-α-hydroxyphosphonic acid exo-3a. The use of …

Enantioselective hydrogenation of β-ketophosphonates with chiral Ru (II) catalysts

X Tao, W Li, X Ma, X Li, W Fan, L Zhu… - The Journal of …, 2012 - ACS Publications
Enantioselective Hydrogenation of β-Ketophosphonates with Chiral Ru(II) Catalysts | The
Journal of Organic Chemistry ACS ACS Publications C&EN CAS Find my institution Log In The …

Asymmetric reaction of α-diazomethylphosphonates with α-ketoesters to access optically active α-diazo-β-hydroxyphosphonate derivatives

F Du, J Zhou, Y Peng - Organic Letters, 2017 - ACS Publications
The first example for asymmetric reaction of diazomethylphosphonates with α-ketoesters
was realized in the catalysis of hydroquinidine-derived bifunctional thiourea. A methodology …

E-Factor minimized hydrophosphonylation of aldehydes catalyzed by polystyryl-BEMP under solvent-free conditions

T Angelini, S Bonollo, D Lanari, F Pizzo… - Organic & Biomolecular …, 2013 - pubs.rsc.org
An efficient protocol for the hydrophosphonylation of aromatic and aliphatic aldehydes
catalyzed by PS-BEMP under solvent-free conditions (SolFC) has been reported. Addition …