Sulfonyl fluorides as targets and substrates in the development of new synthetic methods

TSB Lou, MC Willis - Nature Reviews Chemistry, 2022 - nature.com
The advent of sulfur (vi)-fluoride exchange (SuFEx) processes as transformations with click-
like reactivity has invigorated research into electrophilic species featuring a sulfur–fluorine …

Click chemistry strategies for the accelerated synthesis of functional macromolecules

Z Geng, JJ Shin, Y **, CJ Hawker - Journal of Polymer Science, 2021 - Wiley Online Library
Click chemistry is one of the most powerful strategies for constructing polymeric soft
materials with precise control over architecture and functionality. In this review, we provide a …

High-performing polysulfate dielectrics for electrostatic energy storage under harsh conditions

H Li, BS Chang, H Kim, Z **e, A Lainé, L Ma, T Xu… - Joule, 2023 - cell.com
High-capacity polymer dielectrics that operate with high efficiencies under harsh
electrification conditions are essential components for advanced electronics and power …

The growing applications of SuFEx click chemistry

AS Barrow, CJ Smedley, Q Zheng, S Li… - Chemical Society …, 2019 - pubs.rsc.org
SuFEx (Sulfur Fluoride Exchange) is a modular, next generation family of click reactions,
geared towards the rapid and reliable assembly of functional molecules. This review …

Advances in the construction of diverse SuFEx linkers

D Zeng, WP Deng, X Jiang - National Science Review, 2023 - academic.oup.com
Sulfur fluoride exchange (SuFEx), a new generation of click chemistry, was first presented by
Sharpless, Dong and co-workers in 2014. Owing to the high stability and yet efficient …

Fluorination Strategy Towards Symmetry Breaking of Boron‐centered Tetrahedron for Poly‐fluorinated Optical Crystals

H Qiu, F Li, C **, Z Yang, J Li, S Pan… - Angewandte …, 2024 - Wiley Online Library
Borate crystals can be chemically and functionally modified by the fluorination strategy,
which encourages the identification of emerging fluorooxoborates with a structure and set of …

Sulfur fluoride exchange

JA Homer, L Xu, N Kayambu, Q Zheng… - Nature Reviews …, 2023 - nature.com
Click chemistry is a conceptual strategy to rapidly synthesize and discover functional
molecules. Sulfur fluoride exchange (SuFEx) is a click reaction that has revolutionized …

SuFExable polymers with helical structures derived from thionyl tetrafluoride

S Li, G Li, B Gao, SP Pujari, X Chen, H Kim, F Zhou… - Nature …, 2021 - nature.com
Sulfur (vi) fluoride exchange (SuFEx) is a category of click chemistry that enables covalent
linking of modular units through sulfur (vi) connective hubs. The efficiency of SuFEx and the …

The emerging applications of sulfur (VI) fluorides in catalysis

C Lee, AJ Cook, JE Elisabeth, NC Friede… - ACS …, 2021 - ACS Publications
The past decade has witnessed remarkable growth of catalytic transformations in organic
sulfur (VI) fluoride chemistry. This Perspective concentrates exclusively on foundational …

Radical Hydro‐Fluorosulfonylation of Unactivated Alkenes and Alkynes

P Wang, H Zhang, M Zhao, S Ji, L Lin… - Angewandte Chemie …, 2022 - Wiley Online Library
Recently, radical fluorosulfonylation is emerging as an appealing approach for the synthesis
of sulfonyl fluorides, which are highly in demand in various disciplines, particularly in …