Perspective: Outstanding theoretical questions in polymer-nanoparticle hybrids

SK Kumar, V Ganesan, RA Riggleman - The Journal of chemical …, 2017 - pubs.aip.org
This topical review discusses the theoretical progress made in the field of polymer
nanocomposites, ie, hybrid materials created by mixing (typically inorganic) nanoparticles …

Tunable rheology of dense soft deformable colloids

D Vlassopoulos, M Cloitre - Current opinion in colloid & interface science, 2014 - Elsevier
In the last two decades, advances in synthetic, experimental and modeling/simulation
methodologies have considerably enhanced our understanding of colloidal suspension …

Polymers at interfaces and the interactions in colloidal dispersions

A Vrij - Pure and Applied Chemistry, 1976 - degruyter.com
Solutions of different polymers in the same solvent are incompatible as a rule and show
phase separation when they are mixed. H incompatibility is also to be observed in systems …

Gelation of particles with short-range attraction

PJ Lu, E Zaccarelli, F Ciulla, AB Schofield, F Sciortino… - Nature, 2008 - nature.com
Nanoscale or colloidal particles are important in many realms of science and technology.
They can dramatically change the properties of materials, imparting solid-like behaviour to a …

Characterization of polymer nanocomposite interphase and its impact on mechanical properties

D Ciprari, K Jacob, R Tannenbaum - Macromolecules, 2006 - ACS Publications
The structure of the interphase, a region between nanoparticle fillers and the bulk polymer
matrix in a particle reinforced composite, was investigated using two different approaches …

Theory and simulation studies of effective interactions, phase behavior and morphology in polymer nanocomposites

V Ganesan, A Jayaraman - Soft Matter, 2014 - pubs.rsc.org
Polymer nanocomposites are a class of materials that consist of a polymer matrix filled with
inorganic/organic nanoscale additives that enhance the inherent macroscopic (mechanical …

Depletion-induced phase separation in colloid–polymer mixtures

R Tuinier, J Rieger, CG De Kruif - Advances in colloid and interface science, 2003 - Elsevier
Phase separation can be induced in a colloidal dispersion by adding non-adsorbing
polymers. Depletion of polymer around the colloidal particles induces an effective attraction …

Representability problems for coarse-grained water potentials

ME Johnson, T Head-Gordon, AA Louis - The Journal of chemical …, 2007 - pubs.aip.org
The use of an effective intermolecular potential often involves a compromise between more
accurate, complex functional forms and more tractable simple representations. To study this …

Gelation in model colloid− polymer mixtures

J Bergenholtz, WCK Poon, M Fuchs - Langmuir, 2003 - ACS Publications
Mode coupling theory (MCT) is used to model gel formation in mixtures of colloidal particles
and nonadsorbing polymer. The polymer induces an effective, short-range attraction among …

Perspective: The Asakura Oosawa model: A colloid prototype for bulk and interfacial phase behavior

K Binder, P Virnau, A Statt - The Journal of chemical physics, 2014 - pubs.aip.org
In many colloidal suspensions, the micrometer-sized particles behave like hard spheres, but
when non-adsorbing polymers are added to the solution a depletion attraction (of entropic …