Molecular magnetic materials based on 4d and 5d transition metals

XY Wang, C Avendaño, KR Dunbar - Chemical Society Reviews, 2011 - pubs.rsc.org
The study of paramagnetic compounds based on 4d and 5d transition metals is an emerging
research topic in the field of molecular magnetism. An essential driving force for the interest …

The impact of ligands upon topology and functionality of octacyanidometallate-based assemblies

B Nowicka, T Korzeniak, O Stefańczyk… - Coordination Chemistry …, 2012 - Elsevier
Complete overview of octacyanidometallate polymetallic assemblies is presented from a
novel viewpoint of the importance of incorporated ligands. The ligands are classified …

Magnetic interactions in one-, two-, and three-dimensional assemblies of dinuclear ruthenium carboxylates

M Mikuriya, D Yoshioka, M Handa - Coordination Chemistry Reviews, 2006 - Elsevier
Dinuclear ruthenium complexes which have metal–metal bonds within a paddlewheel
dinuclear core are currently recognized, because of their unique magnetic properties, as …

Crystal structure, charge-transfer-induced spin transition, and photoreversible magnetism in a cyano-bridged cobalt− tungstate bimetallic assembly

S Ohkoshi, Y Hamada, T Matsuda… - Chemistry of …, 2008 - ACS Publications
This paper describes the crystal structure, magnetic properties, and photoreversible
magnetic properties of CoII3 [WV (CN) 8] 2 (pyrimidine) 4· 6H2O. We found that complexes …

A decade of octacyanides in polynuclear molecular materials

B Sieklucka, R Podgajny, T Korzeniak… - European Journal of …, 2011 - Wiley Online Library
The aim and the scope of this review is to show the results of ten years of research following
the first reports on magnetic and photomagnetic assemblies constructed from [M (CN) 8] n …

Integration of Trinuclear Triangle Copper (II) Secondary Building Units in Octacyanidometallates (IV)-Based Frameworks

O Stefanczyk, K Kumar, TY Pai, G Li… - Inorganic …, 2022 - ACS Publications
The design and synthesis of high-dimensional materials based on secondary building
blocks (SBUs) play a pivotal role in the further development of functional molecular …

Molecule-based magnetic materials based on dinuclear ruthenium carboxylate and octacyanotungstate

M Mikuriya, D Yoshioka, A Borta, D Luneau… - New Journal of …, 2011 - pubs.rsc.org
Two structurally different polymeric complexes consisting of ruthenium (II, III) pivalate ([Ru2
(piv)] 4+)(Hpiv= pivalic acid) and octacyanotungstate (V)([W (CN) 8] 3−) ions,[{Ru2 (piv) 4} …

A neutral paddlewheel-type diruthenium (III) complex with benzamidinato ligands: Synthesis, crystal structure, magnetism, and electrochemical and absorption …

Y Kataoka, S Mikami, H Sakiyama, M Mitsumi… - Polyhedron, 2017 - Elsevier
A new neutral diruthenium (III) complex coordinated with benzamidinato (bam) ligands,[Ru 2
(bam) 4 Cl 2]· H 2 O (1), was synthesized and characterized, and its electronic structure was …

An unprecedented up-field shift in the 13 C NMR spectrum of the carboxyl carbons of the lantern-type dinuclear complex TBA [Ru 2 (O 2 CCH 3) 4 Cl 2](TBA+= tetra (n …

Y Hiraoka, T Ikeue, H Sakiyama, F Guégan… - Dalton …, 2015 - pubs.rsc.org
A large up-field shift (− 763 ppm) has been observed for the carboxyl carbons of the
dichlorido complex TBA [Ru2 (O2CCH3) 4Cl2](TBA+= tetra (n-butyl) ammonium cation) in …

Cyano-Bridged Gadolinium–Tungstate Bimetallic One-Dimensional Chains with a Dimethylacetamide Ligand

W Kosaka, K Hashimoto… - Bulletin of the Chemical …, 2007 - academic.oup.com
Abstract Reaction of GdIII (NO) 3· 6H2O and (Bu3NH) 3 [WV (CN) 8](Bu3N= tributylamine) in
N, N-dimethylacetamide (DMA) yielded two types of Gd–W bimetal assemblies with …