Block copolymers form the basis of the most ubiquitous materials such as thermoplastic
elastomers, bridge interphases in polymer blends, and are fundamental for the development …

Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization
(CLRP) technique that enables the design of well-defined, functional and complex …

Recent progress in surface-initiated polymerization enables the deliberate polymer
modification of nanoscopic surfaces with high levels of precision. This has given rise to the …

This Review describes the application of nitroxides to synthesis and polymer chemistry. The
synthesis and physical properties of nitroxides are discussed first. The largest section …

Since its introduction in the early 1990s, nitroxide-mediated radical polymerization (NMP)
has been widely adopted for the preparation of a panoply of new polymer architectures …

The strength of multi-scale modeling to support the fundamental understanding and design
of radical polymerization processes is illustrated, considering both controlled and free …

The extraordinary scientific development of controlled radical polymerization (CRP)
contrasts with the very limited number of commercially available products derived from these …

Due to the academic and industrial interest of Nitroxide Mediated Polymerization (NMP), a
lot of investigations have focused on the kinetics of this process. During the last decade …

A new alkoxyamine (methyl 2-((4-benzoylphenyl)((1-methoxy-2-methyl-1-oxopropan-2-yl)
oxy) amino)-2-methylpropanoate 4) bearing a chromophore group directly linked to the …

Since its discovery, controlled/living radical polymerization (CLRP) has proven to be a
mature technology for building tailor-made (block) copolymers, functional polymers and …