Conspectus Aluminum is the most abundant metal in the earth's crust at 8%, and it is also
widely available domestically in many countries worldwide, which ensures a stable supply …

Organobismuth‐catalyzed transfer hydrogenation has recently been disclosed as an
example of low‐valent Bi redox catalysis. However, its mechanistic details have remained …

Lewis acid sites (LAS) at the CHA (001) and CHA (101) surfaces are investigated regarding
their activity for MeOH-mediated hydrogen transfer reactions from MeOH to alkenes, yielding …

We report the synthesis of cationic 2, 6-bisiminopyridine organoaluminum complexes,[(BIP)
AlR2]+, as stable BArF4–or PF6–salts, and their reversible single-electron reduction into …

The dimerization of nitrogen monoxide (NO) is highly relevant in homo-and heterogeneous
biochemical and environmental redox processes, but a broader understanding is …

Low-coordinate heteroleptic zinc hydrides are catalytically important but rare and
synthetically challenging. We herein report three-coordinate monomeric zinc hydride on a 2 …

Herein, we report the preparation and characterization of the Group 13 metal complexes of a
tripodal tris (nitroxide)-based ligand, designated (TriNOx3–) M (M= Al (1), Ga (2), In (3)) …

Diiminopyridines (DIMPYs) are a unique ligand class capable of multi-site substitution to fine
tune coordination. This ligand framework offers multiple binding modes and the potential for …

This dissertation discusses the synthesis and characterization of aluminum (III)(Al 3+)
complexes with the non-innocent ligands bis (enol) amine (H 3 ONO) and di (imino) pyridine …