The emerging field of organometallic catalysis has shifted towards research on Earth-
abundant transition metals due to their ready availability, economic advantage, and novel …

Borrowing hydrogen is a process that is used to diversify the synthetic utility of commodity
alcohols. A catalyst first oxidizes an alcohol by removing hydrogen to form a reactive …

Rapidly emerging application of organometallic manganese complexes incorporating less
elaborated mono-and bidentate donor ligands in catalytic hydrogenation, transfer …

A homogeneous manganese‐catalyzed cross‐coupling of two secondary alcohols for the
divergent synthesis of γ‐disubstituted alcohols and β‐disubstituted ketones is reported …

Catalytic hydrogen transfer reactions have enormous academic and industrial applications
for the production of diverse molecular scaffolds. Over the past few decades, precious late …

Herein we report the synthesis of primary and secondary amines by nitrile hydrogenation,
employing a borrowing hydrogenation strategy. A class of phosphine-free manganese (I) …

Herein, a phosphine-free pincer ruthenium (III) catalyzed β-alkylation of secondary alcohols
with primary alcohols to α-alkylated ketones and two different secondary alcohols to β …

The alkylation of ketones or secondary alcohols using alcohols as alkylating agents via
hydrogen borrowing strategy presents a powerful method for the synthesis of ɑ‐alkylated …

Acceptorless alcohol dehydrogenation is a powerful reaction in sustainable synthesis. When
combined in a tandem reaction with dehydrogenative coupling or hydrogen borrowing …

We report a visible-light-induced iron-catalyzed α-alkylation of ketones. The photocatalytic
system is based on the single diaminocyclopentadienone iron tricarbonyl complex. Two …