Resha** of metal nanoparticles under reaction conditions

B Zhu, J Meng, W Yuan, X Zhang… - Angewandte Chemie …, 2020 - Wiley Online Library
The shape of metal nanoparticles (NPs) is one of the key factors determining their catalytic
reactivity. Recent in situ TEM observations show that dynamic resha** of metal NPs …

Directing reaction pathways via in situ control of active site geometries in PdAu single-atom alloy catalysts

M Ouyang, KG Papanikolaou, A Boubnov… - Nature …, 2021 - nature.com
The atomic scale structure of the active sites in heterogeneous catalysts is central to their
reactivity and selectivity. Therefore, understanding active site stability and evolution under …

Recent progresses on structural reconstruction of nanosized metal catalysts via controlled-atmosphere transmission electron microscopy: a review

M Tang, W Yuan, Y Ou, G Li, R You, S Li, H Yang… - Acs …, 2020 - ACS Publications
Metal catalysts are of great importance in the modern chemical industry. It is well-known that
the structures of metal catalysts determine their properties. However, recent studies …

The chemical (not mechanical) paradigm of thermodynamics of colloid and interface science

G Kaptay - Advances in Colloid and Interface Science, 2018 - Elsevier
In the most influential monograph on colloid and interfacial science by Adamson three
fundamental equations of “physical chemistry of surfaces” are identified: the Laplace …

Periodic structural changes in Pd nanoparticles during oscillatory CO oxidation reaction

T Ghosh, JM Arce-Ramos, WQ Li, H Yan… - Nature …, 2022 - nature.com
Nanoparticle (NP) catalysts are ubiquitous in energy systems, chemical production, and
reducing the environmental impact of many industrial processes. Under reactive …

Operando insights into nanoparticle transformations during catalysis

A Bergmann, B Roldan Cuenya - Acs Catalysis, 2019 - ACS Publications
Nanostructured materials play an important role in today's chemical industry, acting as
catalysts in heterogeneous thermal and electrocatalytic processes for chemical energy …

Structural changes in noble metal nanoparticles during CO oxidation and their impact on catalyst activity

SW Chee, JM Arce-Ramos, W Li, A Genest… - Nature …, 2020 - nature.com
The dynamical structure of a catalyst determines the availability of active sites on its surface.
However, how nanoparticle (NP) catalysts re-structure under reaction conditions and how …

Reconstruction of supported metal nanoparticles in reaction conditions

M Duan, J Yu, J Meng, B Zhu, Y Wang… - Angewandte …, 2018 - Wiley Online Library
Metal nanoparticles (NPs) dispersed on a high‐surface‐area support are normally used as
heterogeneous catalysts. Recent in situ experiments have shown that structure …

Resha** Dynamics of Gold Nanoparticles under H2 and O2 at Atmospheric Pressure

A Chmielewski, J Meng, B Zhu, Y Gao, H Guesmi… - ACS …, 2019 - ACS Publications
Despite intensive research efforts, the nature of the active sites for O2 and H2 adsorption/
dissociation by supported gold nanoparticles (NPs) is still an unresolved issue in …

In situ TEM studies of the shape evolution of Pd nanocrystals under oxygen and hydrogen environments at atmospheric pressure

X Zhang, J Meng, B Zhu, J Yu, S Zou, Z Zhang… - Chemical …, 2017 - pubs.rsc.org
We demonstrate an atomic scale TEM observation of shape evolutions of Pd nanocrystals
under oxygen and hydrogen environments at atmospheric pressure. Combined with multi …