Critical advances and future opportunities in upcycling commodity polymers

C Jehanno, JW Alty, M Roosen, S De Meester… - Nature, 2022 - nature.com
The vast majority of commodity plastics do not degrade and therefore they permanently
pollute the environment. At present, less than 20% of post-consumer plastic waste in …

“Functional upcycling” of polymer waste towards the design of new materials

O Guselnikova, O Semyonov, E Sviridova… - Chemical Society …, 2023 - pubs.rsc.org
Diversification of polymer waste recycling is one of the solutions to improve the current
environmental scenario. Upcycling is a promising strategy for converting polymer waste into …

Transition-metal-catalyzed silylation and borylation of C–H bonds for the synthesis and functionalization of complex molecules

IF Yu, JW Wilson, JF Hartwig - Chemical Reviews, 2023 - ACS Publications
The functionalization of C–H bonds in organic molecules containing functional groups has
been one of the holy grails of catalysis. One synthetically important approach to the diverse …

Catalytic Upcycling of Polyolefins

J Sun, J Dong, L Gao, YQ Zhao, H Moon… - Chemical …, 2024 - ACS Publications
The large production volumes of commodity polyolefins (specifically, polyethylene,
polypropylene, polystyrene, and poly (vinyl chloride)), in conjunction with their low unit …

Catalytic upcycling of high-density polyethylene via a processive mechanism

A Tennakoon, X Wu, AL Paterson, S Patnaik, Y Pei… - Nature Catalysis, 2020 - nature.com
The overconsumption of single-use plastics is creating a global waste catastrophe, with
widespread environmental, economic and health-related consequences. Here we show that …

Sustainable developments in polyolefin chemistry: Progress, challenges, and outlook

XY Wang, Y Gao, Y Tang - Progress in Polymer Science, 2023 - Elsevier
Polyolefins are the largest-scale synthetic plastics and play a key role in modern society.
Their production consumes huge amounts of fossil-derived monomer feedstocks, which …

From trash to treasure: Chemical recycling and upcycling of commodity plastic waste to fuels, high-valued chemicals and advanced materials

F Zhang, F Wang, X Wei, Y Yang, S Xu, D Deng… - Journal of Energy …, 2022 - Elsevier
Of all the existing materials, plastics are no doubt among the most versatile ones. However,
the extreme increases in plastic production as well as the difficulty of the material for …

Polyolefins and polystyrene as chemical resources for a sustainable future: challenges, advances, and prospects

CWS Yeung, JYQ Teo, XJ Loh, JYC Lim - ACS Materials Letters, 2021 - ACS Publications
Nonbiodegradable plastics with inert and saturated C–C backbones comprise the majority of
global annual plastics produced, including the ubiquitous polyolefins (polyethylene and …

100th Anniversary of macromolecular science viewpoint: Toward catalytic chemical recycling of waste (and future) plastics

JC Worch, AP Dove - ACS Macro Letters, 2020 - ACS Publications
The current global materials economy has long been inefficient due to unproductive reuse
and recycling efforts. Within the wider materials portfolio, plastics have been revolutionary to …

Evolution of C–H bond functionalization from methane to methodology

JF Hartwig - Journal of the American Chemical Society, 2016 - ACS Publications
This Perspective presents the fundamental principles, the elementary reactions, the initial
catalytic systems, and the contemporary catalysts that have converted C–H bond …