We report a highly enantioselective radical-based hydroamination of enol esters with
sulfonamides jointly catalyzed by an Ir photocatalyst, Brønsted base, and tetrapeptide thiol …

Modeling indicates the presence of a region of low electronic density (a “σ-hole”) on group
14 elements, and this offers an explanation for the ability of these elements to act as …

Over the past two decades, many researchers have been interested in “taming” the reactive
free radical intermediate and utilizing it in enantioselective transformations. This review …

N-Methyl-d-aspartate receptors (NMDARs) are glutamate-gated ion channels that play a
crucial role in excitatory synaptic transmission. However, the overactivation of NMDARs can …

Comprehensive Summary In the past two decades, the development of asymmetric radical
reactions has achieved tremendous progress, which has emerged as a powerful tool for the …

Additions of one to two equivalents of Lewis acids that include magnesium salts to free-
radical reduction reactions involving ester functionalized radicals and (1R, 2S, 5R) …

A new class of dithiostannanes and dithiogermanes have been prepared from 1, 1 '-
binaphthyl-2, 2 '-dithiol and 3, 3 '-bis (trimethylsilyl)-1, 1 '-binaphtho-2, 2 '-dithiol. While …

2-Iodo-1, 7, 7-trimethylbicyclo [2.2. 1] hept-2-ene 27 was prepared in two steps from
camphor 23. Halogen–metal exchange using butyllithium followed by addition of the …

2α-(Arylseleno) cholestan-3-ones (3), 2α-(arylseleno) cholest-4-en-3-ones (4), and 4β-
(arylseleno)-24-nor-5β-cholan-3-ones (5) were prepared and their stabilities toward …

An overview on the use of bile acid‐based compounds able to catalyze transformations,
control the stereochemical course of a given reaction, recognize and bind other molecules …