N-heterocyclic carbenes in late transition metal catalysis

S Diez-Gonzalez, N Marion, SP Nolan - Chemical Reviews, 2009 - ACS Publications
N-Heterocyclic carbenes (NHCs) are cyclic carbenes bearing at least one R-amino
substituent. 1 The most common subclasses of NHCs are represented in Chart 1. Early work …

The Development of L2X2RuCHR Olefin Metathesis Catalysts:  An Organometallic Success Story

TM Trnka, RH Grubbs - Accounts of Chemical Research, 2001 - ACS Publications
In recent years, the olefin metathesis reaction has attracted widespread attention as a
versatile carbon− carbon bond-forming method. Many new applications have become …

Ruthenium-based heterocyclic carbene-coordinated olefin metathesis catalysts

GC Vougioukalakis, RH Grubbs - Chemical reviews, 2010 - ACS Publications
The fascinating story of olefin (or alkene) metathesis (eq 1) began almost five decades ago,
when Anderson and Merckling reported the first carbonrcarbon double-bond rearrangement …

Efficient and recyclable monomeric and dendritic Ru-based metathesis catalysts

SB Garber, JS Kingsbury, BL Gray… - Journal of the American …, 2000 - ACS Publications
Several highly active, recoverable and recyclable Ru-based metathesis catalysts are
presented. The crystal structure of Ru complex 5, bearing a 1, 3-dimesityl-4, 5 …

Synthesis and Applications of RuCl2(CHR')(PR3)2:  The Influence of the Alkylidene Moiety on Metathesis Activity

P Schwab, RH Grubbs, JW Ziller - Journal of the American …, 1996 - ACS Publications
The reactions of RuCl2 (PPh3) 3 with a number of diazoalkanes were surveyed, and
alkylidene transfer to give RuCl2 (CHR)(PPh3) 2 (R= Me (1), Et (2)) and RuCl2 (CH-p …

Olefin metathesis and beyond

A Fürstner - Angewandte Chemie International Edition, 2000 - Wiley Online Library
The advent of well‐defined catalysts for olefin metathesis which combine high activity,
durability, and excellent tolerance towards polar functional groups has revolutionized the …

Recent advances in olefin metathesis and its application in organic synthesis

RH Grubbs, S Chang - Tetrahedron, 1998 - Elsevier
Recent advances in olefin metathesis, focusing on the areas of ring-closing olefin
metathesis (RCM) and cross metathesis, are reviewed. Among numerous complexes which …

Selective carbon–carbon bond cleavage of cyclopropanols

TR McDonald, LR Mills, MS West… - Chemical …, 2020 - ACS Publications
The carbon–carbon (C–C) bond cleavage of cyclopropanols is a wide area of research with
much current activity. This review highlights new developments in this area over the past two …

Evolution of the nitrogen cycle and its influence on the biological sequestration of CO2 in the ocean

PG Falkowski - Nature, 1997 - nature.com
Over geological time, photosynthetic carbon fixation in the oceans has exceeded respiratory
oxidation of organic carbon. The imbalance between the two processes has resulted in the …

[BOOK][B] Olefin metathesis and metathesis polymerization

KJ Ivin, JC Mol - 1997 - books.google.com
This book is a follow-up to Ivins Olefin Metathesis,(Academic Press, 1983). Bringing the
standard text in the field up to date, this Second Edition is a result of rapid growth in the field …