Calcium‐based sustainable chemical technologies for total carbon recycling

KS Rodygin, YA Vikenteva, VP Ananikov - ChemSusChem, 2019 - Wiley Online Library
Calcium carbide, a stable solid compound composed of two atoms of carbon and one of
calcium, has proven its effectiveness in chemical synthesis, due to the safety and …

Calcium carbide: Versatile synthetic applications, green methodology and sustainability

KS Rodygin, MS Ledovskaya… - European Journal of …, 2021 - Wiley Online Library
Acetylene is a key building block for organic chemistry and potentially can be involved in a
diverse range of synthetic transformations. However, critical analysis of practical …

Machine learning assisted high-throughput screening of transition metal single atom based superb hydrogen evolution electrocatalysts

M Umer, S Umer, M Zafari, M Ha, R Anand… - Journal of Materials …, 2022 - pubs.rsc.org
Carbon-based transition metal (TM) single-atom catalysts (SACs) have shown great
potential toward electrochemical water splitting and H2 production. Given that two …

Metal-mediated and metal-catalyzed reactions under mechanochemical conditions

A Porcheddu, E Colacino, L De Luca, F Delogu - ACS Catalysis, 2020 - ACS Publications
The extraordinary impact of metal-based complexes on synthetic methods is still recognized
nowadays, and attempts are currently undertaken to further extend the use of metal-assisted …

A general asymmetric copper-catalysed Sonogashira C(sp3)–C(sp) coupling

XY Dong, YF Zhang, CL Ma, QS Gu, FL Wang, ZL Li… - Nature Chemistry, 2019 - nature.com
Continued development of the Sonogashira coupling has made it a well established and
versatile reaction for the straightforward formation of C–C bonds, forging the carbon …

1, 2‐Difunctionalization of Acetylene Enabled by Light

S Lü, Z Wang, X Gao, K Chen… - Angewandte Chemie …, 2023 - Wiley Online Library
Although the direct conversion of gaseous acetylene into value‐added liquid commodity
chemicals is becoming increasingly attractive, the majority of the established methodologies …

Melt polymerization synthesis of a class of robust self-shaped olefin-linked COF foams as high-efficiency separators

P Zhang, Z Wang, Y Yang, S Wang, T Wang… - Science China …, 2022 - Springer
The practical applications of crystalline porous materials toward industrial separations
require sha** them into robust monoliths (eg, foams). The current methods are often …

Acetylene group, friend or foe in medicinal chemistry

TT Talele - Journal of Medicinal Chemistry, 2020 - ACS Publications
The use of an acetylene (ethynyl) group in medicinal chemistry coincides with the launch of
the Journal of Medicinal Chemistry in 1959. Since then, the acetylene group has been …

Thiol-Yne click chemistry of acetylene-enabled macrocyclization

S Lü, Z Wang, S Zhu - Nature Communications, 2022 - nature.com
Macrocycles have fascinated scientists for over half a century due to their aesthetically
appealing structures and broad utilities in chemical, material, and biological research …

Rhodium-catalyzed annulative coupling using vinylene carbonate as an oxidizing acetylene surrogate

K Ghosh, Y Nishii, M Miura - ACS Catalysis, 2019 - ACS Publications
Transition-metal-catalyzed C–H activation and subsequent oxidative cyclization with alkynes
has been a powerful tool for the synthesis of polycyclic aromatic compounds. Despite the …