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Transition-metal-catalyzed functionalization of alkynes with organoboron reagents: new trends, mechanistic insights, and applications
J Corpas, P Mauleon, RG Arrayás, JC Carretero - ACS Catalysis, 2021 - ACS Publications
Catalytic functionalization of alkynes with organoboron reagents provides a straightforward
access to stereochemically defined multisubstituted alkenes, which are structural motifs …
access to stereochemically defined multisubstituted alkenes, which are structural motifs …
Nickel‐Catalyzed Arylative Cyclizations of Alkyne‐and Allene‐Tethered Electrophiles using Arylboron Reagents
SM Gillbard, HW Lam - Chemistry–A European Journal, 2022 - Wiley Online Library
The use of arylboron reagents in metal‐catalyzed domino addition–cyclization reactions is a
well‐established strategy for the preparation of diverse, highly functionalized carbo‐and …
well‐established strategy for the preparation of diverse, highly functionalized carbo‐and …
Recent progress in arylmetalative cyclization/annulation of functionalized alkynes with organoboranes
Achieving complex molecular assemblies in modular modes is always one of the top
priorities of the organic chemist. Cyclization/annulation of functionalized alkynes through …
priorities of the organic chemist. Cyclization/annulation of functionalized alkynes through …
Nickel‐Catalyzed Enantioselective Synthesis of 2, 3, 4‐Trisubstituted 3‐Pyrrolines
The development of synthetic methods to produce highly functionalized chiral 3‐pyrrolines is
of indisputable importance because of their prevalence in natural and synthetic bioactive …
of indisputable importance because of their prevalence in natural and synthetic bioactive …
Nonclassical Arylative Meyer–Schuster Rearrangement through Ni-Catalyzed Inner-Sphere Acyloxy Migration
J Bae, W Lee, HS Hwang, S Kim, J Kang, N Iqbal… - ACS …, 2023 - ACS Publications
A Ni (II)-catalyzed unconventional Meyer–Schuster rearrangement (MSR) is paired with
cross-coupling through inner-sphere acyloxy migration. Various propargyl acetates react …
cross-coupling through inner-sphere acyloxy migration. Various propargyl acetates react …
Enantioselective Nickel-Catalyzed Reductive anti-Arylative Annulation of Alkyne-Tethered Malononitriles to Construct Quaternary Stereocenters
WM Liu, Z Lu, Q Wei, WB Liu - Organic Letters, 2023 - ACS Publications
A nickel-catalyzed reductive desymmetrizing annulation of alkyne-tethered malononitriles
and (hetero) aryl iodides is reported for the access of cyclohexenones containing an α-all …
and (hetero) aryl iodides is reported for the access of cyclohexenones containing an α-all …
A Sequential Activation of Alkyne and C–H Bonds for the Tandem Cyclization and Annulation of Alkynols and Maleimides through Cooperative Sc (III) and Cp*-Free …
RK Gurram, M Rajesh, MK Reddy Singam… - Organic …, 2020 - ACS Publications
[4+ 2] oxidative Diels–Alder reaction of readily available alkynols with maleimide is achieved
for the rapid access of pthalimide-fused multicyclic compounds. The reaction is proposed to …
for the rapid access of pthalimide-fused multicyclic compounds. The reaction is proposed to …
Enantioselective Nickel‐Catalyzed anti‐Arylmetallative Cyclizations onto Acyclic Ketones
H Green, SP Argent, HW Lam - Chemistry–A European Journal, 2021 - Wiley Online Library
Domino reactions involving nickel‐catalyzed additions of (hetero) arylboronic acids to
alkynes, followed by cyclization of the alkenylnickel intermediates onto tethered acyclic …
alkynes, followed by cyclization of the alkenylnickel intermediates onto tethered acyclic …
Recent progress towards transition-metal-catalyzed arylative cyclization/annulation reactions with boronic acids
Boron-containing organometallic compounds had been always fascinated organic chemists
because it has been widely used in carbon-carbon bond formation reactions such as the …
because it has been widely used in carbon-carbon bond formation reactions such as the …
Enantioselective nickel-catalyzed anti-arylmetallative cyclizations onto acyclic electron-deficient alkenes
SM Gillbard, H Green, SP Argent… - Chemical Communications, 2021 - pubs.rsc.org
Enantioselective nickel-catalyzed anti -arylmetallative cyclizations onto acyclic electron-deficient
alkenes - Chemical Communications (RSC Publishing) DOI:10.1039/D1CC01166A Royal …
alkenes - Chemical Communications (RSC Publishing) DOI:10.1039/D1CC01166A Royal …