Transition-metal-catalyzed functionalization of alkynes with organoboron reagents: new trends, mechanistic insights, and applications

J Corpas, P Mauleon, RG Arrayás, JC Carretero - ACS Catalysis, 2021 - ACS Publications
Catalytic functionalization of alkynes with organoboron reagents provides a straightforward
access to stereochemically defined multisubstituted alkenes, which are structural motifs …

Nickel‐Catalyzed Arylative Cyclizations of Alkyne‐and Allene‐Tethered Electrophiles using Arylboron Reagents

SM Gillbard, HW Lam - Chemistry–A European Journal, 2022 - Wiley Online Library
The use of arylboron reagents in metal‐catalyzed domino addition–cyclization reactions is a
well‐established strategy for the preparation of diverse, highly functionalized carbo‐and …

Recent progress in arylmetalative cyclization/annulation of functionalized alkynes with organoboranes

M Rajesh, GR Kumar - Asian Journal of Organic Chemistry, 2023 - Wiley Online Library
Achieving complex molecular assemblies in modular modes is always one of the top
priorities of the organic chemist. Cyclization/annulation of functionalized alkynes through …

Nickel‐Catalyzed Enantioselective Synthesis of 2, 3, 4‐Trisubstituted 3‐Pyrrolines

SD Tambe, CH Ka, HS Hwang, J Bae… - Angewandte Chemie …, 2022 - Wiley Online Library
The development of synthetic methods to produce highly functionalized chiral 3‐pyrrolines is
of indisputable importance because of their prevalence in natural and synthetic bioactive …

Nonclassical Arylative Meyer–Schuster Rearrangement through Ni-Catalyzed Inner-Sphere Acyloxy Migration

J Bae, W Lee, HS Hwang, S Kim, J Kang, N Iqbal… - ACS …, 2023 - ACS Publications
A Ni (II)-catalyzed unconventional Meyer–Schuster rearrangement (MSR) is paired with
cross-coupling through inner-sphere acyloxy migration. Various propargyl acetates react …

Enantioselective Nickel-Catalyzed Reductive anti-Arylative Annulation of Alkyne-Tethered Malononitriles to Construct Quaternary Stereocenters

WM Liu, Z Lu, Q Wei, WB Liu - Organic Letters, 2023 - ACS Publications
A nickel-catalyzed reductive desymmetrizing annulation of alkyne-tethered malononitriles
and (hetero) aryl iodides is reported for the access of cyclohexenones containing an α-all …

A Sequential Activation of Alkyne and C–H Bonds for the Tandem Cyclization and Annulation of Alkynols and Maleimides through Cooperative Sc (III) and Cp*-Free …

RK Gurram, M Rajesh, MK Reddy Singam… - Organic …, 2020 - ACS Publications
[4+ 2] oxidative Diels–Alder reaction of readily available alkynols with maleimide is achieved
for the rapid access of pthalimide-fused multicyclic compounds. The reaction is proposed to …

Enantioselective Nickel‐Catalyzed anti‐Arylmetallative Cyclizations onto Acyclic Ketones

H Green, SP Argent, HW Lam - Chemistry–A European Journal, 2021 - Wiley Online Library
Domino reactions involving nickel‐catalyzed additions of (hetero) arylboronic acids to
alkynes, followed by cyclization of the alkenylnickel intermediates onto tethered acyclic …

Recent progress towards transition-metal-catalyzed arylative cyclization/annulation reactions with boronic acids

RK Maurya, S Bhukta, K Kishor, R Chatterjee… - Journal of Molecular …, 2023 - Elsevier
Boron-containing organometallic compounds had been always fascinated organic chemists
because it has been widely used in carbon-carbon bond formation reactions such as the …

Enantioselective nickel-catalyzed anti-arylmetallative cyclizations onto acyclic electron-deficient alkenes

SM Gillbard, H Green, SP Argent… - Chemical Communications, 2021 - pubs.rsc.org
Enantioselective nickel-catalyzed anti -arylmetallative cyclizations onto acyclic electron-deficient
alkenes - Chemical Communications (RSC Publishing) DOI:10.1039/D1CC01166A Royal …