Water oxidation with transition metal catalysts with non-innocent ligands and its mechanisms
Transition metal complexes acting as catalysts towards water oxidation concern a
challenging research topic with high relevance in solar and fuel conversion technologies …
challenging research topic with high relevance in solar and fuel conversion technologies …
Functional metal complexes based on bridging “imino”-quinonoid ligands
B Sarkar, D Schweinfurth, N Deibel… - Coordination Chemistry …, 2015 - Elsevier
Dihydroxy-1, 4-benzoquinone (dhbq) has been extensively used as a ligand for generating
mono and polynuclear complexes. In recent years, new ligand classes have been …
mono and polynuclear complexes. In recent years, new ligand classes have been …
Manifestations of noninnocent ligand behavior
W Kaim - Inorganic Chemistry, 2011 - ACS Publications
The potential of redox-active ligands to behave “noninnocently” in transition-metal
coordination compounds is reflected with respect to various aspects and situations. These …
coordination compounds is reflected with respect to various aspects and situations. These …
Assigning ligand redox levels in complexes of 2-aminophenolates: Structural signatures
R Mukherjee - Inorganic Chemistry, 2020 - ACS Publications
The purpose of this Viewpoint is to provide a broad-ranging update of advances in the
coordination chemistry of redox-active (noninnocent) 2-aminophenolates, with emphasis on …
coordination chemistry of redox-active (noninnocent) 2-aminophenolates, with emphasis on …
Evidence for Bidirectional Noninnocent Behavior of a Formazanate Ligand in Ruthenium Complexes
A Mandal, B Schwederski, J Fiedler, W Kaim… - Inorganic …, 2015 - ACS Publications
Redox series of the complexes [Ru (L)(L′) 2] n, L= 1, 5-diphenyl-3-(4-tolyl)-formazanate
and L′= 2, 4-pentanedionate (acac–), 2, 2′-bipyridine (bpy), or 2-phenylazopyridine …
and L′= 2, 4-pentanedionate (acac–), 2, 2′-bipyridine (bpy), or 2-phenylazopyridine …
Adducts of transition metal complexes with redox-active ligands: the structure and spin-state-switching rearrangements
AA Starikova, VI Minkin - Russian Chemical Reviews, 2018 - iopscience.iop.org
The currently available literature data on the synthesis, molecular and electronic structure of
mixed-ligand complexes (adducts) of transition metals (chromium, manganese, iron, cobalt …
mixed-ligand complexes (adducts) of transition metals (chromium, manganese, iron, cobalt …
NO and NO2 as non-innocent ligands: A comparison
W Kaim, A Das, J Fiedler, S Záliš, B Sarkar - Coordination Chemistry …, 2020 - Elsevier
The potential of environmentally and technically relevant NO 2 for non-innocent ligand
behavior in coordination compounds is being evaluated in comparison with the well-studied …
behavior in coordination compounds is being evaluated in comparison with the well-studied …
Ru-Complex Framework toward Aerobic Oxidative Transformations of β-Diketiminate and α-Ketodiimine
The impact of the {Ru (acac) 2}(acac–= acetylacetonate) framework on the transformations
of C–H and C–H/C–C bonds of coordinated β-diketiminate and ketodiimine scaffolds …
of C–H and C–H/C–C bonds of coordinated β-diketiminate and ketodiimine scaffolds …
Electronic structure alternatives in nitrosylruthenium complexes
GK Lahiri, W Kaim - Dalton Transactions, 2010 - pubs.rsc.org
Coordination compounds [Ru (NO) Ln] containing an electro-active metal and potentially
non-innocent ligands NO (and L) can have ground state electronic structures formulated as …
non-innocent ligands NO (and L) can have ground state electronic structures formulated as …
Sensitivity of a strained C–C single bond to charge transfer: redox activity in mononuclear and dinuclear ruthenium complexes of bis (arylimino) acenaphthene (BIAN) …
The new compounds [Ru (acac) 2 (BIAN)], BIAN= bis (arylimino) acenaphthene (aryl= Ph
(1a), 4-MeC6H4 (2a), 4-OMeC6H4 (3a), 4-ClC6H4 (4a), 4-NO2C6H4 (5a)), were …
(1a), 4-MeC6H4 (2a), 4-OMeC6H4 (3a), 4-ClC6H4 (4a), 4-NO2C6H4 (5a)), were …