Understanding specific ion effects and the Hofmeister series

KP Gregory, GR Elliott, H Robertson, A Kumar… - Physical Chemistry …, 2022 - pubs.rsc.org
Specific ion effects (SIE), encompassing the Hofmeister Series, have been known for more
than 130 years since Hofmeister and Lewith's foundational work. SIEs are ubiquitous and …

Molecular reactions at aqueous interfaces

MF Ruiz-Lopez, JS Francisco… - Nature Reviews …, 2020 - nature.com
This Review aims to critically analyse the emerging field of chemical reactivity at aqueous
interfaces. The subject has evolved rapidly since the discovery of the so-called 'on-water …

Biomolecular condensates are characterized by interphase electric potentials

AE Posey, A Bremer, NA Erkamp, A Pant… - Journal of the …, 2024 - ACS Publications
Biomolecular condensates form via processes that combine phase separation and
reversible associations of multivalent macromolecules. Condensates can be two-or …

Weakly hydrated anions bind to polymers but not monomers in aqueous solutions

BA Rogers, HI Okur, C Yan, T Yang, J Heyda… - Nature Chemistry, 2022 - nature.com
Weakly hydrated anions help to solubilize hydrophobic macromolecules in aqueous
solutions, but small molecules comprising the same chemical constituents precipitate out …

Surface stratification determines the interfacial water structure of simple electrolyte solutions

Y Litman, KY Chiang, T Seki, Y Nagata, M Bonn - Nature Chemistry, 2024 - nature.com
The distribution of ions at the air/water interface plays a decisive role in many natural
processes. Several studies have reported that larger ions tend to be surface-active, implying …

Hofmeister phenomena: an update on ion specificity in biology

P Lo Nostro, BW Ninham - Chemical reviews, 2012 - ACS Publications
Specific ion effects occur everywhere. They occur in bulk solutions and at interfaces
(air/water, oil/water, solid/water, macromolecule/water, etc.). They are even found in …

Mercury physicochemical and biogeochemical transformation in the atmosphere and at atmospheric interfaces: a review and future directions

PA Ariya, M Amyot, A Dastoor, D Deeds… - Chemical …, 2015 - ACS Publications
Mercury is a fascinating fluid metal that exists as liquid at 25 C (0 C= 273 K). This silver
colored d-block heavy metal exhibits noble-gas-like characteristics and solidifies at a …

Water as an active constituent in cell biology

P Ball - Chemical reviews, 2008 - ACS Publications
When Szent-Györgyi called water the “matrix of life”, 1 he was echoing an old sentiment.
Paracelsus in the 16th century said that “water was the matrix of the world and of all its …

[BUCH][B] Theory of Molecular Fluids: Volume 2: Applications

CG Gray, KE Gubbins, CG Joslin - 2011 - books.google.com
Existing texts on the statistical mechanics of liquids treat only spherical molecules. However,
nearly all fluids of practical interest are composed of non-spherical molecules that are often …

Electrostatic charging due to separation of ions at interfaces: contact electrification of ionic electrets

LS McCarty, GM Whitesides - … Chemie International Edition, 2008 - Wiley Online Library
This Review discusses ionic electrets: their preparation, their mechanisms of formation, tools
for their characterization, and their applications. An electret is a material that has a …