Elemental and chemically specific X-ray fluorescence imaging of biological systems

MJ Pushie, IJ Pickering, M Korbas, MJ Hackett… - Chemical …, 2014 - ACS Publications
From the perspective of a chemist, biology confers a rich variety of roles on a number of
metal ions. It is widely agreed that a large fraction of the genomic output of living things …

Potential of food hydrolyzed proteins and peptides to chelate iron or calcium and enhance their absorption

ME Walters, R Esfandi, A Tsopmo - Foods, 2018 - mdpi.com
Iron and calcium are two essential micronutrients that have strong effects on nutrition and
human health because of their involvement in several biological and redox processes. Iron …

X-ray-induced photo-chemistry and X-ray absorption spectroscopy of biological samples

GN George, IJ Pickering, MJ Pushie… - Journal of …, 2012 - journals.iucr.org
As synchrotron light sources and optics deliver greater photon flux on samples, X-ray-
induced photo-chemistry is increasingly encountered in X-ray absorption spectroscopy …

X-ray fluorescence microscopy methods for biological tissues

MJ Pushie, NJ Sylvain, H Hou, MJ Hackett… - Metallomics, 2022 - academic.oup.com
Synchrotron-based X-ray fluorescence microscopy is a flexible tool for identifying the
distribution of trace elements in biological specimens across a broad range of sample sizes …

Microfluidic liquid sheets as large-area targets for high repetition XFELs

DJ Hoffman, TB Van Driel, T Kroll… - Frontiers in molecular …, 2022 - frontiersin.org
The high intensity of X-ray free electron lasers (XFELs) can damage solution-phase samples
on every scale, ranging from the molecular or electronic structure of a sample to the …

X-ray absorption spectroscopy of biological samples. A tutorial

R Ortega, A Carmona, I Llorens… - Journal of Analytical Atomic …, 2012 - pubs.rsc.org
X-ray absorption spectroscopy (XAS) is an element specific spectroscopy sensitive to the
local chemical and structural order of the absorber element. XAS is nowadays increasingly …

A multimodal spectroscopic imaging method to characterize the metal and macromolecular content of proteinaceous aggregates (“amyloid plaques”)

KL Summers, N Fimognari, A Hollings, M Kiernan… - Biochemistry, 2017 - ACS Publications
Alzheimer's disease (AD) is a major international health and economic concern. A key
pathological feature of AD is so-called “amyloid-β-plaques”, or “Aβ-plaques”, which are …

Advances in element speciation analysis of biomedical samples using synchrotron-based techniques

F Porcaro, S Roudeau, A Carmona, R Ortega - TrAC Trends in Analytical …, 2018 - Elsevier
Synchrotron-radiation X-ray absorption spectroscopy (XAS) is a direct method for speciation
analysis with atomic resolution, providing information about the local chemical environment …

Better together: potential of co-culture microorganisms to enhance bioleaching of rare earth elements from monazite

H Fathollahzadeh, MJ Hackett, HN Khaleque… - Bioresource technology …, 2018 - Elsevier
The aim of this study was to develop continuous bioleaching of monazite by combining
heterotrophic and autotrophic acidophilic microorganisms. The results showed that a co …

Photon-induced, timescale, and electrode effects critical for the in situ X-ray spectroscopic analysis of electrocatalysts: the water oxidation case

HJ King, M Fournier, SA Bonke, E Seeman… - The Journal of …, 2019 - ACS Publications
In situ experiments combining X-ray absorption spectroscopy (XAS) and electrochemistry
have now become an indispensable tool for understanding the mechanisms of operation …