Microkinetic modeling: a tool for rational catalyst design

AH Motagamwala, JA Dumesic - Chemical Reviews, 2020 - ACS Publications
The design of heterogeneous catalysts relies on understanding the fundamental surface
kinetics that controls catalyst performance, and microkinetic modeling is a tool that can help …

Recent developments of nanocatalyzed liquid-phase hydrogen generation

C Wang, D Astruc - Chemical Society Reviews, 2021 - pubs.rsc.org
Hydrogen is the most effective and sustainable carrier of clean energy, and liquid-phase
hydrogen storage materials with high hydrogen content, reversibility and good …

Single-atom Rh/N-doped carbon electrocatalyst for formic acid oxidation

Y **ong, J Dong, ZQ Huang, P **n, W Chen… - Nature …, 2020 - nature.com
To meet the requirements of potential applications, it is of great importance to explore new
catalysts for formic acid oxidation that have both ultra-high mass activity and CO resistance …

Single-Atomic Cu with Multiple Oxygen Vacancies on Ceria for Electrocatalytic CO2 Reduction to CH4

Y Wang, Z Chen, P Han, Y Du, Z Gu, X Xu… - ACS Catalysis, 2018 - ACS Publications
The electrocatalytic reduction of CO2 into value-added chemicals such as hydrocarbons has
the potential for supplying fuel energy and reducing environmental hazards, while the …

Metal-support interactions in heterogeneous catalytic hydrogen production of formic acid

S Bai, A Jia, J Song, S Cao, N Wang, X Liu - Chemical Engineering Journal, 2023 - Elsevier
Hydrogen (H 2) is regarded as a novel energy carrier with huge development potential, and
it will be essential in future clean energy systems. Given the existing challenges in direct H 2 …

Theoretical heterogeneous catalysis: scaling relationships and computational catalyst design

J Greeley - Annual review of chemical and biomolecular …, 2016 - annualreviews.org
Scaling relationships are theoretical constructs that relate the binding energies of a wide
variety of catalytic intermediates across a range of catalyst surfaces. Such relationships are …

Recent Progress in Electrocatalytic Methanation of CO2 at Ambient Conditions

R Zhao, P Ding, P Wei, L Zhang, Q Liu… - Advanced Functional …, 2021 - Wiley Online Library
Electrochemical CO2 reduction under ambient conditions is a promising pathway for
conversion of CO2 into value‐added products. In recent years, great achievements have …

Strong Metal–Support Interaction for 2D Materials: Application in Noble Metal/TiB2 Heterointerfaces and their Enhanced Catalytic Performance for Formic Acid …

R Li, Z Liu, QT Trinh, Z Miao, S Chen, K Qian… - Advanced …, 2021 - Wiley Online Library
Strong metal–support interaction (SMSI) is a phenomenon commonly observed on
heterogeneous catalysts. Here, direct evidence of SMSI between noble metal and 2D TiB2 …

Alternate biobased route to produce δ-Decalactone: Elucidating the role of solvent and hydrogen evolution in catalytic transfer hydrogenation

MI Alam, TS Khan, MA Haider - ACS Sustainable Chemistry & …, 2018 - ACS Publications
A widely used food and flavor compound, δ-decalactone (DDL), was produced from catalytic
transfer hydrogenation of 6-amyl-α-pyrone (6PP), which is a biomass-based platform …

Single Isolated Pd2+ Cations Supported on N-Doped Carbon as Active Sites for Hydrogen Production from Formic Acid Decomposition

DA Bulushev, M Zacharska, EV Shlyakhova… - ACS …, 2016 - ACS Publications
Single-site heterogeneous catalysis with isolated Pd atoms was reported earlier, mainly for
oxidation reactions and for Pd catalysts supported on oxide surfaces. In the present work, we …