Expanded theory of H-and J-molecular aggregates: the effects of vibronic coupling and intermolecular charge transfer

NJ Hestand, FC Spano - Chemical reviews, 2018 - ACS Publications
The electronic excited states of molecular aggregates and their photophysical signatures
have long fascinated spectroscopists and theoreticians alike since the advent of Frenkel …

Perylene diimide-based Hj-and hJ-aggregates: the prospect of exciton band shape engineering in organic materials

A Oleson, T Zhu, IS Dunn, D Bialas, Y Bai… - The Journal of …, 2019 - ACS Publications
The exciton band dispersion in π-stacks of conjugated organic chromophores is a critical
factor in determining the photophysical response and transport properties. In such stacks …

Direct observation of ultrafast coherent exciton dynamics in helical π-stacks of self-assembled perylene bisimides

J Sung, P Kim, B Fimmel, F Würthner, D Kim - Nature communications, 2015 - nature.com
Ever since the discovery of dye self-assemblies in nature, there have been tremendous
efforts to exploit biomimetic supramolecular assemblies for tailored artificial photon …

Quantifying charge transfer energies at donor–acceptor interfaces in small-molecule solar cells with constrained DFTB and spectroscopic methods

R Scholz, R Luschtinetz, G Seifert… - Journal of physics …, 2013 - iopscience.iop.org
Charge transfer states around the donor–acceptor interface in an organic solar cell
determine the device performance in terms of the open circuit voltage. In the present work …

Solution-processable singlet fission photovoltaic devices

L Yang, M Tabachnyk, SL Bayliss, ML Böhm… - Nano …, 2015 - ACS Publications
We demonstrate the successful incorporation of a solution-processable singlet fission
material, 6, 13-bis (triisopropylsilylethynyl) pentacene (TIPS-pentacene), into photovoltaic …

High fill factor and open circuit voltage in organic photovoltaic cells with diindenoperylene as donor material

J Wagner, M Gruber, A Hinderhofer… - Advanced Functional …, 2010 - Wiley Online Library
Small‐molecule photovoltaic cells using diindenoperylene (DIP) as a new donor material in
combination with the fullerene C60 as an electron acceptor are demonstrated. In addition to …

Extended-charge-transfer excitons in crystalline supramolecular photocatalytic scaffolds

NJ Hestand, RV Kazantsev… - Journal of the …, 2016 - ACS Publications
Coupling among chromophores in molecular assemblies is responsible for phenomena
such as resonant energy transfer and intermolecular charge transfer. These processes are …

Absorption, circular dichroism, and photoluminescence in perylene diimide bichromophores: polarization-dependent H-and J-aggregate behavior

KA Kistler, CM Pochas, H Yamagata… - The Journal of …, 2012 - ACS Publications
Using a single-mode Holstein Hamiltonian with through-space excitonic couplings
evaluated quantum mechanically, the absorption, circular dichroism, and …

Crystallochromy of perylene pigments: Interference between Frenkel excitons and charge-transfer states

L Gisslén, R Scholz - Physical Review B—Condensed Matter and Materials …, 2009 - APS
The optical properties of perylene-based pigments are arising from the interplay between
neutral molecular excitations and charge transfer between adjacent molecules. In the …

Analysis of the UV/Vis and CD Spectral Line Shapes of Carotenoid Assemblies: Spectral Signatures of Chiral H-Aggregates

FC Spano - Journal of the American Chemical Society, 2009 - ACS Publications
Using vibronic exciton theory we evaluate the absorption and CD spectra of lutein and lutein
diacetate aggregates, which have previously been described as card-packed H-aggregates …