A Perspective of our work in the development of innovative synthetic methods within the
discipline of Process Research and Development is presented. Through an overview of …

A brief account of the major developments of palladium-catalyzed cross-coupling during the
last two decades is highlighted chronologically, with an emphasis on the personal …

Strategies for the development of Pd catalysts based on utilization of L2Pd and LPd species,
beyond the contributions of the 2010 Nobel Laureates Richard Heck, Ei-ichi Negishi, and …

A highly active and efficient catalyst system derived from a palladium precatalyst and
monophosphine ligands 1 or 2 for the Suzuki− Miyaura cross-coupling reaction of heteroaryl …

A preeminent challenge in alkene difunctionalization is the control of regio-, diastereo-, and
enantioselectivity. In this Perspective, a Pd/Cu-cooperative catalytic system for alkene …

Carbon‐Carbon bond forming reactions using Suzuki‐Miyaura cross‐coupling (SMC)
technology to construct aryl‐aryl, aryl‐heteroaryl or heteroaryl‐heteroaryl linkages continues …

A convenient one-pot C− H alkenylation/electrocyclization/aromatization sequence has
been developed for the synthesis of highly substituted pyridine derivatives from alkynes and …

New technology is reported that enables Negishi couplings to be run under sustainable, far
greener conditions. Thus, ppm Pd‐containing nanoparticles (NPs) have been developed …

Here, we report on a new single‐molecule‐switching concept based on the coordination‐
sphere‐dependent spin state of FeII species. The perpendicular arrangement of two …

A wide variety of bench-stable potassium heteroaryltrifluoroborates were prepared, and
general reaction conditions were developed for their cross-coupling to aryl and heteroaryl …