Organofluorine chemistry: Promising growth areas and challenges

LV Politanskaya, GA Selivanova… - Russian Chemical …, 2019 - iopscience.iop.org
Currently, the chemistry of organofluorine compounds is a leading and rapidly develo**
area of organic chemistry. Fluorine present in a molecule largely determines its specific …

Modern Trends of Organic Chemistry in Russian Universities

AI Konovalov, IS Antipin, VA Burilov… - Russian Journal of …, 2018 - Springer
This review is devoted to the scientific achievements of the departments of organic chemistry
in higher schools of Russia within the past decade.

Trifluoromethanesulfonic acid in organic synthesis

AN Kazakova, AV Vasilyev - Russian Journal of Organic Chemistry, 2017 - Springer
The review analyzes data published in the past decade on the use of
trifluoromethanesulfonic acid (triflic acid, CF 3 SO 3 H, TfOH) in organic synthesis, in …

Reactions of linear conjugated dienone structures with arenes under superelectrophilic activation conditions. An experimental and theoretical study of intermediate …

MA Kochurin, AR Ismagilova, DN Zakusilo… - New Journal of …, 2022 - pubs.rsc.org
Reactions of linear conjugated dienone structures ArCHCHCHCHC (O) X, 1, 5-diarylpenta-
2, 4-dien-1-ones (X= Ar′), 5-phenylpenta-2, 4-dienoic acid (Ar= Ph, X= OH) and its methyl …

Synthesis of α-(Trifluoromethyl) styrenes and 1, 3-Di (trifluoromethyl) indanes via Electrophilic Activation of TMS Ethers of (Trifluoromethyl) benzyl Alcohols in Brønsted …

OV Khoroshilova, IA Boyarskaya… - The Journal of Organic …, 2022 - ACS Publications
TMS ethers of CF3-benzyl alcohols (and their heterocyclic analogues) undergo elimination
of TMSOH molecule with the formation of α-(trifluoromethyl) styrenes in yields of up to 90 …

[PDF][PDF] Современные тенденции органической химии в университетах России

АИ Коновалов, ИС Антипин, ВА Бурилов… - Журнал …, 2018 - researchgate.net
5. Кафедра органической химии Московского государственного университета им. МВ
Ломоносова. 6. Кафедра химии Российского национального исследовательского …

Superacid‐Promoted Synthesis of CF3‐Indenes Using Brominated CF3‐Enones

RO Iakovenko, AN Kazakova… - European Journal of …, 2017 - Wiley Online Library
The reactions of 3‐bromo‐and 3, 4‐dibromo‐CF3‐enones with superacids were studied.
Protonation of these CF3‐enones with FSO3H resulted in the formation of cationic species …

Generation and NMR Study of Short-Lived and Reactive Trifluoroalkyl Carbocations of the α-Halogenothiophene Series in Brønsted Superacids: Reactions of the …

OV Khoroshilova, AV Vasilyev - The Journal of Organic Chemistry, 2020 - ACS Publications
Protonation of oxygen in the side chain of the Me3SiO group (followed by the elimination of
Me3SiOH) and protonation of the thiophene ring in 2-chloro (or bromo)-5-(1′-Me3SiO-1 …

Generation and reactions of thiocarbonyl S-(2, 2, 2-trifluoroethanides). Synthesis of trifluoromethylated 1, 3-dithiolanes, thiiranes and alkenes

MK Kowalski, E Obijalska, G Mlostoń… - Journal of Fluorine …, 2017 - Elsevier
Abstract The 'in situ'generated 1, 1, 1-trifluorodiazoethane reacts with thioketones as C= S
dipolarophiles in a two-phase system (DCM/H 2 O) at room temperature to yield …

Controlling the selectivity of an intramolecular Friedel–Crafts alkylation with alkenes using selenium under mild conditions

MH Liao, M Zhang, DH Hu, RH Zhang… - Organic & …, 2020 - pubs.rsc.org
An efficiently divergent intramolecular Friedel–Crafts alkylation by unactivated alkenes with
seleniranium ion-controlled Markovnikov/anti-Markovnikov specificities under mild …