Recent advances in supramolecular fullerene chemistry

X Chang, Y Xu, M von Delius - Chemical Society Reviews, 2024 - pubs.rsc.org
Fullerene chemistry has come a long way since 1990, when the first bulk production of C60
was reported. In the past decade, progress in supramolecular chemistry has opened some …

New horizons for catalysis disclosed by supramolecular chemistry

G Olivo, G Capocasa, D Del Giudice… - Chemical Society …, 2021 - pubs.rsc.org
The adoption of a supramolecular approach in catalysis promises to address a number of
unmet challenges, ranging from activity (unlocking of novel reaction pathways) to selectivity …

Fluorescent cyclophanes and their applications

I Roy, AHG David, PJ Das, JP David… - Chemical Society …, 2022 - pubs.rsc.org
With the serendipitous discovery of crown ethers by Pedersen more than half a century ago
and the subsequent introduction of host–guest chemistry and supramolecular chemistry by …

Mechanically interlocked materials. Rotaxanes and catenanes beyond the small molecule

S Mena-Hernando, EM Pérez - Chemical Society Reviews, 2019 - pubs.rsc.org
A mechanical bond presents a combination of the best features of covalent and
supramolecular chemistries (stability and structural integrity), plus a unique dynamic nature …

A dodecamethoxy [6] cycloparaphenylene consisting entirely of hydroquinone ethers: unveiling in-plane aromaticity through a rotaxane structure

N Narita, Y Kurita, K Osakada, T Ide, H Kawai… - Nature …, 2023 - nature.com
Abstract [n] Cycloparaphenylenes ([n] CPPs, where n is the number of phenylene groups),
consisting of 1, 4-linked phenylene unit, have attracted much attention due to their cyclic π …

The supramolecular chemistry of strained carbon nanohoops

Y Xu, M von Delius - Angewandte Chemie International Edition, 2020 - Wiley Online Library
Since 1996, a growing number of strained macrocycles, comprising only sp2‐or sp‐
hybridized carbon atoms within the ring, have become synthetically accessible, with the [n] …

Chiral carbon nanorings: synthesis, properties and hierarchical self‐assembly of chiral ternary complexes featuring a narcissistic chiral self‐recognition for chiral …

Y Fan, J He, L Liu, G Liu, S Guo, Z Lian, X Li… - Angewandte …, 2023 - Wiley Online Library
We report the synthesis and chiroptical properties of novel chiral carbon nanorings Sp‐/Rp‐
[12] PCPP containing a planar chiral [2.2] PCP unit, and demonstrate that Sp‐/Rp‐[12] PCPP …

Synthesis of C60/[10]CPP‐Catenanes by Regioselective, Nanocapsule‐Templated Bingel Bis‐Addition

FM Steudel, E Ubasart, L Leanza… - Angewandte Chemie …, 2023 - Wiley Online Library
The addition of two unsymmetric malonate esters to the Buckminster fullerene C60 can lead
to 22 spectroscopically distinguishable isomeric products and therefore represents a …

Lemniscular [16] cycloparaphenylene: a radially conjugated figure-eight aromatic molecule

K Senthilkumar, M Kondratowicz, T Lis… - Journal of the …, 2019 - ACS Publications
A cycloparaphenylene-based molecular lemniscate (CPPL) was obtained in a short
synthesis involving masked p-phenylene equivalents. The strained figure-eight geometry of …

[n]Cycloparaphenylene‐Pillar[5]arene Bismacrocycles: Their Circularly Polarized Luminescence and Multiple Guest Recognition Properties

Y Xu, F Steudel, MY Leung, B **a… - Angewandte Chemie …, 2023 - Wiley Online Library
Both pillar [n] arenes (P [n] As) and [n] cycloparaphenylenes ([n] CPPs) play an important
role in supramolecular chemistry. Herein, we report the precise synthesis of two …