Hydrogen and dihydrogen bonds in the reactions of metal hydrides
The dihydrogen bond an interaction between a transition-metal or main-group hydride (M
H) and a protic hydrogen moiety (H X) is arguably the most intriguing type of hydrogen …
H) and a protic hydrogen moiety (H X) is arguably the most intriguing type of hydrogen …
Ion pairing in transition-metal organometallic chemistry
A Macchioni - Chemical reviews, 2005 - ACS Publications
The ion-pair concept1-4 was introduced in 1926 by Bjerrum5 to account for the behavior of
ionophores (species, such as alkali halides, that are ionic in the crystalline state and exist as …
ionophores (species, such as alkali halides, that are ionic in the crystalline state and exist as …
Diverse world of unconventional hydrogen bonds
NV Belkova, ES Shubina… - Accounts of chemical …, 2005 - ACS Publications
This Account presents our view of unconventional intermolecular hydrogen bonds (HBs) for
organometallic complexes and transition-metal or main-group hydrides. Over the past …
organometallic complexes and transition-metal or main-group hydrides. Over the past …
Rationally designed fluorescence 'turn-on'sensor for Cu 2+
A rationally designed, coumarin-based fluorescent sensor imino-coumarin (IC) displays high
selectivity for Cu2+ over a variety of competing metal ions in aqueous solution with a …
selectivity for Cu2+ over a variety of competing metal ions in aqueous solution with a …
pH-dependent selective transfer hydrogenation of α, β-unsaturated carbonyls in aqueous media utilizing half-sandwich ruthenium (II) complexes
Half-sandwich ruthenium (II) PTA complexes bearing the 1, 2-dihydropentalenyl (C8H9-, Dp)
and indenyl (C9H7-, Ind) ancillary ligands have been synthesized and characterized using …
and indenyl (C9H7-, Ind) ancillary ligands have been synthesized and characterized using …
Investigate oxoazolidine-2, 4-dione based eutectic mixture via DFT calculations and SAR
In this work, DFT calculations for the designed eutectic mixtures (EMs) using oxoazolidine 2,
4-dione (OZD) and zinc chloride (ZnCl2) are done. The interaction between the hydrogen …
4-dione (OZD) and zinc chloride (ZnCl2) are done. The interaction between the hydrogen …
Protonation of transition-metal hydrides: a not so simple process
The protonation of a transition-metal hydride is a formally simple process between a proton
donor and a proton acceptor with several potential basic centres. The detailed mechanism is …
donor and a proton acceptor with several potential basic centres. The detailed mechanism is …
Hydrogen/deuterium exchange reactions of olefins with deuterium oxide mediated by the carbonylchlorohydrido‐tris (triphenylphosphine) ruthenium (II) Complex
SKS Tse, P Xue, Z Lin, G Jia - Advanced synthesis & catalysis, 2010 - Wiley Online Library
The catalytic properties of several ruthenium, osmium and rhodium hydride complexes for
hydrogen/deuterium (H/D) exchange between olefins and deuterium oxide (D2O) were …
hydrogen/deuterium (H/D) exchange between olefins and deuterium oxide (D2O) were …
[HTML][HTML] Mechanistic considerations on catalytic H/D exchange mediated by organometallic transition metal complexes
The purpose of this review is to analyze the different reaction mechanisms of the H/D
exchange on organic substrates catalyzed by transition metal complexes in homogeneous …
exchange on organic substrates catalyzed by transition metal complexes in homogeneous …
Facile synthesis of polypeptoids bearing bulky sidechains via urea accelerated ring-opening polymerization of α-amino acid N-substituted N-carboxyanhydrides
Polypeptoids, as synthetic mimics of polypeptides, exhibit a variety of biological functions
and excellent proteolytic stability. Polypeptoids can be synthesized by the ring-opening …
and excellent proteolytic stability. Polypeptoids can be synthesized by the ring-opening …