Generalized Kohn‐Sham energy decomposition analysis and its applications

P Su, Z Tang, W Wu - Wiley Interdisciplinary Reviews …, 2020 - Wiley Online Library
Energy decomposition analysis (EDA) methods bridge the gap between electronic structure
calculations and conceptual interpretations of molecular interactions. The recently …

Recent advances on the development of NO-releasing molecules (NORMs) for biomedical applications

R Bhowmik, M Roy - European Journal of Medicinal Chemistry, 2024 - Elsevier
Nitric oxide (NO) is an important biological messenger as well as a signaling molecule that
participates in a broad range of physiological events and therapeutic applications in …

Ru (II) based dual nitric oxide donors: electrochemical and photochemical reactivities and vasorelaxant effect with no cytotoxicity

CDS da Silva, KQ Ferreira, CS Meira… - Dalton …, 2023 - pubs.rsc.org
The synthesized complexes, cis-[Ru (NO)(NO2)(phen) 2](PF6) 2 (NONO2P) and cis-[Ru
(NO)(NO2)(bpy) 2](PF6) 2 (NONO2B), were characterized by using elemental analysis …

Probing the origins of activation barriers in nitrous oxide capture reactions by analyzing Lewis acid–base pairs with dimethylxanthene-linked group-13 (P) and group …

ZF Zhang, MD Su - New Journal of Chemistry, 2024 - pubs.rsc.org
Nitrogen oxides, including nitrous oxide (N2O), are undoubtedly classified as greenhouse
gases. In this research, we conducted a theoretical investigation into the N2O capturing …

Formation and Release of NO from Ruthenium Nitrosyl Ammine Complexes [Ru(NH3)5(NO)]2+/3+ in Aqueous Solution: A Theoretical Investigation

GLS Rodrigues, WR Rocha - The Journal of Physical Chemistry B, 2016 - ACS Publications
In this article, density functional theory in conjunction with Monte Carlo statistical mechanical
simulation was used to investigate the electronic structure, reduction potential, solvation …

Conformation, hydration, and ligand exchange process of ruthenium nitrosyl complexes in aqueous solution: Free‐energy calculations by a combination of molecular …

K Kido, M Kaneko - Journal of Computational Chemistry, 2023 - Wiley Online Library
Distribution of solvent molecules near transition‐metal complex is key information to
comprehend the functionality, reactivity, and so forth. However, polarizable continuum …

Synthesis and crystal structure of nitrosoruthenium complexes cis-[Ru (NO) Py 2 Cl 2 (OH)] and cis-[Ru (NO) Py 2 Cl 2 (H 2 O)] Cl. Photoinduced transformations of cis …

AN Makhinya, MA Il'in, RD Yamaletdinov… - New Journal of …, 2016 - pubs.rsc.org
The interaction of K2 [Ru (NO) Cl5] with an excess of pyridine followed by concentration of
the reaction solution afforded two crystalline modifications of cis-[Ru (NO) Py2Cl2 (OH)](1a …

Ligand Electrochemical Parameter Approach to Molecular Design. σ-Donation, π-Back Donation, and Other Metrics in Ruthenium (II) Dinitrogen Complexes

WJ Pietro, ABP Lever - Inorganic Chemistry, 2022 - ACS Publications
Using the density functional theory,[(N2) RuIIL5] n+ species are studied in silico. The
properties of the Ru–N2 bond are derived, including σ-donation, π-back donation, Ru–N …

Advances in bonding and properties of inorganic systems from relativistic calculations in Latin America

D Macleod‐Carey, GF Caramori… - … Journal of Quantum …, 2019 - Wiley Online Library
The inclusion of relativistic effects to understand chemical structures and related properties
brings to the scientific community challenging study cases, showing the rich diversity of …

A DFT study of cis-[Ru (NO)(NO2) bpy (dye) 2] n+ complexes as NO donors

ET da Silva, TU da Silva, K de Carvalho Pougy… - Inorganica Chimica …, 2020 - Elsevier
The synthesis and characterization of a new complex, cis-[Ru (NO)(NO 2) bpy (AO) 2](PF 6)
2, was reported, and the release of NO from ruthenium-nitrosyl complexes with dye ligands …