Vinyl cyclopropanes are amongst the most useful building blocks in organic synthesis. Their
easy opening and capacity to generate dipoles have been exploited for the synthesis of …

Intramolecular aminations of C–H bonds represent an elegant synthetic way to form
important N-heterocycles. If suitable nitrene precursors are employed, organometallic …

We introduce the atomic valence active space (AVAS), a simple and well-defined automated
technique for constructing active orbital spaces for use in multiconfiguration and …

Vinylcyclopropanes (VCPs) are commonly used in transition‐metal‐catalyzed
cycloadditions, and the utilization of their recently realized reactivities to construct new cyclic …

The nucleophilic iron complex Bu4N [Fe (CO) 3 (NO)](TBA [Fe]) catalyzes the direct
intramolecular C− H amination of α‐azidobiaryls and (azidoaryl) alkenes into the …

Racemic cyclopropyl ketones undergo enantioselective rearrangement to deliver the
corresponding dihydrofurans in the presence of a chiral phosphoric acid as the catalyst. The …

Iron‐Catalyzed Intramolecular Aminations of C(sp3)−H Bonds in Alkylaryl Azides - Alt - 2017 -
Angewandte Chemie International Edition - Wiley Online Library Skip to Article Content Skip to …

An organocatalytic Cloke–Wilson rearrangement of cyclopropyl ketones to 2, 3-
dihydrofurans is exploited utilizing the homoconjugate addition process. With 1, 4 …

Efficient and robust approximations to the full configuration interaction (full-CI) method such
as the density matrix renormalization group (DMRG) and the full-CI quantum Monte Carlo …

We report a mild Lewis acid induced isomerization of donor–acceptor cyclopropanes,
containing an alkenyl moiety and diverse electron-withdrawing group (s) at the adjacent …