Organic synthesis using nitroxides
Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …
The Hitchhiker's guide to biocatalysis: recent advances in the use of enzymes in organic synthesis
Enzymes are excellent catalysts that are increasingly being used in industry and academia.
This perspective is primarily aimed at synthetic organic chemists with limited experience …
This perspective is primarily aimed at synthetic organic chemists with limited experience …
The E factor 25 years on: the rise of green chemistry and sustainability
RA Sheldon - Green Chemistry, 2017 - pubs.rsc.org
The global impact, over the last 25 years, of the principles of green chemistry and
sustainability, and the pivotal role of the E factor concept in driving resource efficiency and …
sustainability, and the pivotal role of the E factor concept in driving resource efficiency and …
Broadening the scope of biocatalysis in sustainable organic synthesis
This Review is aimed at synthetic organic chemists who may be familiar with organometallic
catalysis but have no experience with biocatalysis, and seeks to provide an answer to the …
catalysis but have no experience with biocatalysis, and seeks to provide an answer to the …
Aerobic copper-catalyzed organic reactions
SE Allen, RR Walvoord, R Padilla-Salinas… - Chemical …, 2013 - ACS Publications
The chemistry of copper is extremely rich because it can easily access Cu0, CuI, CuII, and
CuIII oxidation states allowing it to act through one-electron or two-electron processes. As a …
CuIII oxidation states allowing it to act through one-electron or two-electron processes. As a …
Copper-catalyzed aerobic oxidations of organic molecules: pathways for two-electron oxidation with a four-electron oxidant and a one-electron redox-active catalyst
SD McCann, SS Stahl - Accounts of Chemical Research, 2015 - ACS Publications
Conspectus Selective oxidation reactions have extraordinary value in organic chemistry,
ranging from the conversion of petrochemical feedstocks into industrial chemicals and …
ranging from the conversion of petrochemical feedstocks into industrial chemicals and …
Fundamentals of green chemistry: efficiency in reaction design
RA Sheldon - Chemical Society Reviews, 2012 - pubs.rsc.org
In this tutorial review, the fundamental concepts underlying the principles of green and
sustainable chemistry-atom and step economy and the E factor-are presented, within the …
sustainable chemistry-atom and step economy and the E factor-are presented, within the …
Practical aerobic oxidations of alcohols and amines with homogeneous copper/TEMPO and related catalyst systems
BL Ryland, SS Stahl - Angewandte Chemie International …, 2014 - Wiley Online Library
Oxidations of alcohols and amines are common reactions in the synthesis of organic
molecules in the laboratory and industry. Aerobic oxidation methods have long been sought …
molecules in the laboratory and industry. Aerobic oxidation methods have long been sought …
Copper‐Catalyzed Aerobic Oxidative C H Functionalizations: Trends and Mechanistic Insights
AE Wendlandt, AM Suess… - Angewandte Chemie …, 2011 - Wiley Online Library
The selective oxidation of C H bonds and the use of O2 as a stoichiometric oxidant
represent two prominent challenges in organic chemistry. Copper (II) is a versatile oxidant …
represent two prominent challenges in organic chemistry. Copper (II) is a versatile oxidant …
Oxidase mimicking nanozyme: Classification, catalytic mechanisms and sensing applications
Z Lin, J Yuan, L Niu, Y Zhang, X Zhang, M Wang… - Coordination Chemistry …, 2024 - Elsevier
Nanozymes are a type of nanomaterials that mimics natural enzymes with biocatalytic
functions. Oxidase is a kind of oxidoreductase which oxidizes hydrogen donor substrates in …
functions. Oxidase is a kind of oxidoreductase which oxidizes hydrogen donor substrates in …