Asymmetric catalysis has been recognized as the most enabling strategy for accessing
chiral molecules in enantioenriched forms. Catalytic asymmetric dearomatization is an …

This Review summarizes the development of catalytic asymmetric dearomatization (CADA)
reactions. The CADA reactions discussed herein include oxidative dearomatization …

Covering: 2000 up to 2019. Catalytic asymmetric dearomatization (CADA) reactions have
witnessed considerable development in recent years. As the most extensively studied sub …

The rapid generation of molecular complexity from simple starting materials is of paramount
importance in synthetic chemistry. The unique combination of high reactivity and high …

Covering: 2011 to 2022 The natural world is a prolific source of some of the most interesting,
rare, and complex molecules known, harnessing sophisticated biosynthetic machinery …

Over the years, alkaloids derived from indole dearomatization, such as indolenine and
indolines have been evolved as promising therapeutic agents due to their important …

A carbene-catalyzed chemoselective reaction of unsymmetric enedials is disclosed. The
reaction provides a concise access to bicyclic furo [2, 3-b] pyrroles derivatives in excellent …

The advent of organic synthesis and the understanding of the molecule as they occurred in
the nineteenth century and were refined in the twentieth century constitute two of the most …

Allyl greift an: Fünfgliedrige Spiroindolenine werden hoch enantioselektiv durch die
iridiumkatalysierte intramolekulare allylierende Desaromatisierung von Indolen aufgebaut …

The main objective of this review is to provide a comprehensive survey of methods used for
stereoselective construction of carbon–nitrogen bonds during the total synthesis of nitrogen …