Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …

Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization
(CLRP) technique that enables the design of well-defined, functional and complex …

The materials of future depend a lot on properties that are due to “non stable” molecules.
Hence, Dynamic Covalent Bonds (DCB) are covalent bonds that are labile under specific …

High-level quantum-chemical methods have been used to study the scope and physical
origin of the significant long-range stabilizing interactions between nonmutually conjugated …

1. INTRODUCTION For more than two decades, from the 1960s to the mid-1980s,
fundamental research in radical chemistry aroused tremedeous interest in the physical …

Predicting or manipulating charge-transfer at semiconductor interfaces, from molecular
electronics to energy conversion, relies on knowledge generated from a kinetic analysis of …

Time-dependent fluorescence spectroscopy has been used to demonstrate significant pH-
dependent electrostatic effects on the kinetics and thermodynamics of hydrogen atom …

Nitroxide-mediated polymerization is now a mature technique, at 35 years of age. During
this time, several variants have been developed: enhanced spin capture polymerization …

In recent decades, quantum chemical calculations (QCC) have increased in accuracy, not
only providing the ranking of chemical reactivities and energy barriers (eg, for optimal …

Conspectus In 1986, Rizzardo et al. discovered the nitroxide-mediated polymerization which
relies on the reversibility of homolysis of the C–ON bond of alkoxyamine R1R2NOR3, a …