Coordination-directed self-assembly of functional polynuclear lanthanide supramolecular architectures

XZ Li, CB Tian, QF Sun - Chemical Reviews, 2022 - ACS Publications
Lanthanide supramolecular chemistry is a fast growing and intriguing research field due to
the unique photophysical, magnetic, and coordination properties of lanthanide ions (LnIII) …

Molecular nanomagnets: a viable path toward quantum information processing?

A Chiesa, P Santini, E Garlatti, F Luis… - Reports on Progress in …, 2024 - iopscience.iop.org
Molecular nanomagnets (MNMs), molecules containing interacting spins, have been a
playground for quantum mechanics. They are characterized by many accessible low-energy …

Single-molecule magnets beyond a single lanthanide ion: the art of coupling

YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …

Increasing the Magnetic Blocking Temperature of Single‐Molecule Magnets

V Vieru, S Gómez‐Coca, E Ruiz… - Angewandte …, 2024 - Wiley Online Library
The synthesis of single‐molecule magnets (SMMs), magnetic complexes capable of
retaining magnetization blocking for a long time at elevated temperatures, has been a major …

Molecular magnetism of lanthanide: Advances and perspectives

Z Zhu, M Guo, XL Li, J Tang - Coordination Chemistry Reviews, 2019 - Elsevier
The discovery of the first example of lanthanide-based single molecule magnets (Ln-SMMs),
a revolutionary progress, marked the beginning of a new age for SMMs, has greatly inspired …

Strategies to quench quantum tunneling of magnetization in lanthanide single molecule magnets

A Swain, T Sharma, G Rajaraman - Chemical Communications, 2023 - pubs.rsc.org
Enhancing blocking temperature (TB) is one of the holy grails in Single Molecule Magnets
(SMMs), as any future potential application in this class of molecules is directly correlated to …

Lanthanide single-molecule magnets

DN Woodruff, REP Winpenny, RA Layfield - Chemical reviews, 2013 - ACS Publications
In the early 1990s, great excitement followed the discovery that a molecular transition metal
coordination compound could, at liquid-helium temperatures, retain magnetization for long …

An air-stable Dy (III) single-ion magnet with high anisotropy barrier and blocking temperature

SK Gupta, T Rajeshkumar, G Rajaraman… - Chemical …, 2016 - pubs.rsc.org
Herein we report air-stable Dy (III) and Er (III) single-ion magnets (SIMs) with pseudo-D5h
symmetry, synthesized from a sterically encumbered phosphonamide, tBuPO (NHiPr) 2 …

A ferrotoroidic candidate with well‐separated spin chains

J Zhang, X Wang, L Zhou, G Liu, DT Adroja… - Advanced …, 2022 - Wiley Online Library
The search of novel quasi‐1D materials is one of the important aspects in the field of
material science. Toroidal moment, the order parameter of ferrotoroidic order, can be …

Recent advances in dysprosium-based single molecule magnets: Structural overview and synthetic strategies

P Zhang, YN Guo, J Tang - Coordination Chemistry Reviews, 2013 - Elsevier
The last few years have seen a huge renaissance in the study of the magnetism of
lanthanide coordination complexes, especially in the field of single molecule magnets …