Redox-active molecular wires incorporating ruthenium (II) σ-arylacetylide complexes for molecular electronics

C Olivier, BS Kim, D Touchard, S Rigaut - Organometallics, 2008 - ACS Publications
The preparation and properties of novel ruthenium carbon-rich complexes for molecular
electronics are reported. The synthetic procedure used in this work led to the first series of …

C7 and C9 Carbon-Rich Bridges in Diruthenium Systems:  Synthesis, Spectroscopic, and Theoretical Investigations of Different Oxidation States

S Rigaut, C Olivier, K Costuas, S Choua… - Journal of the …, 2006 - ACS Publications
Two methodologies of C− C bond formation to achieve organometallic complexes with 7 or 9
conjugated carbon atoms are described. A C7 annelated trans-[Cl (dppe) 2Ru CCC CH C …

Dimolybdenum dimers spaced by phenylene groups: The experimental models for study of electronic coupling

H Lei, X **ao, M Meng, T Cheng, Y Shu, YN Tan… - Inorganica Chimica …, 2015 - Elsevier
This account reviews our recent investigation on the electronic coupling and intramolecular
electron transfer in D–B–A systems constructed by employing covalently bonded [Mo 2] units …

“Chain-Like” Trimetallic Ruthenium Complexes with C7 Carbon-Rich Bridges: Experimental and Theoretical Investigations of Electronic Communication Tuning in …

C Olivier, K Costuas, S Choua, V Maurel… - Journal of the …, 2010 - ACS Publications
In this work, we report the synthesis and the electronic properties of the unique highly
conjugated molecular wires trans-[Cl−(dppe) 2Ru C C(Ph) C− CH(CH3) C− C C−(X) …

Equatorially connected diruthenium (II, III) units toward paramagnetic supramolecular structures with singular magnetic properties

MC Barral, T Gallo, S Herrero… - Inorganic …, 2006 - ACS Publications
The reaction of Ru2Cl (O2CMe)(DPhF) 3 (DPhF= N, N '-diphenylformamidinate) with mono-
and polycarboxylic acids gives a clean substitution of the acetate ligand, leading to the …

Control of the Charge Distribution and Modulation of the Class II–III Transition in Weakly Coupled Mo2–Mo2 Systems

X **ao, CY Liu, Q He, MJ Han, M Meng, H Lei… - Inorganic …, 2013 - ACS Publications
Three novel dimolybdenum dimers [Mo2 (DAniF) 3] 2 (μ-OSCC6H4CSO),[Mo2 (DAniF) 3] 2
(μ-O2CC6H4CS2), and [Mo2 (DAniF) 3] 2 (μ-S2CC6H4CS2)(DAniF= N, N′-di (p-anisyl) …

Paramagnetic Precursors for Supramolecular Assemblies: Selective Syntheses, Crystal Structures, and Electrochemical and Magnetic Properties of Ru2 (O2CMe) 4-n …

P Angaridis, FA Cotton, CA Murillo, D Villagrán… - Inorganic …, 2004 - ACS Publications
Reactions of Ru2 (O2CMe) 4Cl with two formamidines, HDXyl2, 6F= N, N '-di (2, 6-xylyl)
formamidine and HDAniF= N, N '-di (p-anisyl) formamidine, have been investigated with the …

Metal–Metal Electronic Coupling in syn and anti Stereoisomers of Mixed‐Valent (FeCp)2‐, (RhL2)2‐, and (FeCp)(RhL2)‐as‐Indacenediide Ions

S Santi, L Orian, C Durante, EZ Bencze… - … A European Journal, 2007 - Wiley Online Library
The extent of metal–metal electronic coupling was quantified for a series of syn and anti
stereoisomers of (FeCp) 2‐,(RhL2) 2‐and (FeCp)(RhL2)‐(L2= 1, 5‐cyclooctadiene (cod), L …

Uniquely Strong Electronic Communication between [Mo2] Units Linked by Dioxolene Dianions

FA Cotton, CA Murillo, D Villagrán… - Journal of the American …, 2006 - ACS Publications
Unprecedented strong electronic communication has been found in dimolybdenum pairs
containing quadruply bonded Mo2 (DAniF) 3+(DAniF= N, N '-di-p-anisylformamidinate) units …

Selective ligand modification on the periphery of diruthenium compounds: toward new metal-alkynyl scaffolds

WZ Chen, T Ren - Organometallics, 2005 - ACS Publications
Diruthenium compounds Ru2 (D mAni F) 3 (OAc) Cl (1, D mAni F is N, N '-di (m-
methoxyphenyl) formamidinate) and cis-Ru2 (D mAniF) 2 (OAc) 2Cl (6) reacted with N, N ' …