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Connections between the accuracy of rotational constants and equilibrium molecular structures
C Puzzarini, JF Stanton - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
Rotational spectroscopy is the technique of choice for investigating molecular structures in
the gas phase. Indeed, rotational constants are strongly connected to the geometry of the …
the gas phase. Indeed, rotational constants are strongly connected to the geometry of the …
Aromatics and cyclic molecules in molecular clouds: A new dimension of interstellar organic chemistry
MC McCarthy, BA McGuire - The Journal of Physical Chemistry A, 2021 - ACS Publications
Astrochemistry lies at the nexus of astronomy, chemistry, and molecular physics. On the
basis of precise laboratory data, a rich collection of more than 200 familiar and exotic …
basis of precise laboratory data, a rich collection of more than 200 familiar and exotic …
2021 census of interstellar, circumstellar, extragalactic, protoplanetary disk, and exoplanetary molecules
BA McGuire - The Astrophysical Journal Supplement Series, 2022 - iopscience.iop.org
To date, 241 individual molecular species, composed of 19 different elements, have been
detected in the interstellar and circumstellar medium by astronomical observations. These …
detected in the interstellar and circumstellar medium by astronomical observations. These …
Interstellar detection of the highly polar five-membered ring cyanocyclopentadiene
Much like six-membered rings, five-membered rings are ubiquitous in organic chemistry,
frequently serving as the building blocks for larger molecules, including many of biochemical …
frequently serving as the building blocks for larger molecules, including many of biochemical …
Discovery of fulvenallene in TMC-1 with the QUIJOTE line survey
We report the detection of fulvenallene (cC 5 H 4 CCH 2) in the direction of TMC-1 with the
QUIJOTE 1 line survey. Thirty rotational transitions with K a= 0, 1, 2, 3 and J= 9− 15 were …
QUIJOTE 1 line survey. Thirty rotational transitions with K a= 0, 1, 2, 3 and J= 9− 15 were …
Discovery of two isomers of ethynyl cyclopentadiene in TMC-1: Abundances of CCH and CN derivatives of hydrocarbon cycles
We report the detection of two isomers of ethynyl cyclopentadiene (cC 5 H 5 CCH), namely 1-
and 2-ethynyl-1, 3-cyclopentadiene, in the direction of TMC-1. We derive column densities of …
and 2-ethynyl-1, 3-cyclopentadiene, in the direction of TMC-1. We derive column densities of …
Detection of ethynylbenzene in TMC-1 and the interstellar search for 1, 2-diethynylbenzene
D Loru, C Cabezas, J Cernicharo, M Schnell… - Astronomy & …, 2023 - aanda.org
Aims. We investigate the outcome of an electrical discharge of naphthalene and search for
the resulting products in the Taurus Molecular Cloud (TMC-1). Methods. Using chirped pulse …
the resulting products in the Taurus Molecular Cloud (TMC-1). Methods. Using chirped pulse …
A Search for Heterocycles in GOTHAM Observations of TMC-1
We have conducted an extensive search for nitrogen-, oxygen-, and sulfur-bearing
heterocycles toward Taurus Molecular Cloud 1 (TMC-1) using the deep, broadband …
heterocycles toward Taurus Molecular Cloud 1 (TMC-1) using the deep, broadband …
Interstellar detection of 2-cyanocyclopentadiene, C5H5CN, a second five-membered ring toward TMC-1
Using radio observations with the Green Bank Telescope, evidence has now been found for
a second five-membered ring in the dense cloud Taurus Molecular Cloud-1 (TMC-1). Based …
a second five-membered ring in the dense cloud Taurus Molecular Cloud-1 (TMC-1). Based …
Carbon-chain chemistry in the interstellar medium
The presence of carbon-chain molecules in the interstellar medium (ISM) has been known
since the early 1970s and> 130 such species have been identified to date, making up∼ …
since the early 1970s and> 130 such species have been identified to date, making up∼ …