Connections between the accuracy of rotational constants and equilibrium molecular structures

C Puzzarini, JF Stanton - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
Rotational spectroscopy is the technique of choice for investigating molecular structures in
the gas phase. Indeed, rotational constants are strongly connected to the geometry of the …

Aromatics and cyclic molecules in molecular clouds: A new dimension of interstellar organic chemistry

MC McCarthy, BA McGuire - The Journal of Physical Chemistry A, 2021 - ACS Publications
Astrochemistry lies at the nexus of astronomy, chemistry, and molecular physics. On the
basis of precise laboratory data, a rich collection of more than 200 familiar and exotic …

2021 census of interstellar, circumstellar, extragalactic, protoplanetary disk, and exoplanetary molecules

BA McGuire - The Astrophysical Journal Supplement Series, 2022 - iopscience.iop.org
To date, 241 individual molecular species, composed of 19 different elements, have been
detected in the interstellar and circumstellar medium by astronomical observations. These …

Interstellar detection of the highly polar five-membered ring cyanocyclopentadiene

MC McCarthy, KLK Lee, RA Loomis, AM Burkhardt… - Nature …, 2021 - nature.com
Much like six-membered rings, five-membered rings are ubiquitous in organic chemistry,
frequently serving as the building blocks for larger molecules, including many of biochemical …

Discovery of fulvenallene in TMC-1 with the QUIJOTE line survey

J Cernicharo, R Fuentetaja, M Agúndez… - Astronomy & …, 2022 - aanda.org
We report the detection of fulvenallene (cC 5 H 4 CCH 2) in the direction of TMC-1 with the
QUIJOTE 1 line survey. Thirty rotational transitions with K a= 0, 1, 2, 3 and J= 9− 15 were …

Discovery of two isomers of ethynyl cyclopentadiene in TMC-1: Abundances of CCH and CN derivatives of hydrocarbon cycles

J Cernicharo, M Agúndez, RI Kaiser… - Astronomy & …, 2021 - aanda.org
We report the detection of two isomers of ethynyl cyclopentadiene (cC 5 H 5 CCH), namely 1-
and 2-ethynyl-1, 3-cyclopentadiene, in the direction of TMC-1. We derive column densities of …

Detection of ethynylbenzene in TMC-1 and the interstellar search for 1, 2-diethynylbenzene

D Loru, C Cabezas, J Cernicharo, M Schnell… - Astronomy & …, 2023 - aanda.org
Aims. We investigate the outcome of an electrical discharge of naphthalene and search for
the resulting products in the Taurus Molecular Cloud (TMC-1). Methods. Using chirped pulse …

A Search for Heterocycles in GOTHAM Observations of TMC-1

TJ Barnum, MA Siebert, KLK Lee… - The Journal of …, 2022 - ACS Publications
We have conducted an extensive search for nitrogen-, oxygen-, and sulfur-bearing
heterocycles toward Taurus Molecular Cloud 1 (TMC-1) using the deep, broadband …

Interstellar detection of 2-cyanocyclopentadiene, C5H5CN, a second five-membered ring toward TMC-1

KLK Lee, PB Changala, RA Loomis… - The Astrophysical …, 2021 - iopscience.iop.org
Using radio observations with the Green Bank Telescope, evidence has now been found for
a second five-membered ring in the dense cloud Taurus Molecular Cloud-1 (TMC-1). Based …

Carbon-chain chemistry in the interstellar medium

K Taniguchi, P Gorai, JC Tan - Astrophysics and Space Science, 2024 - Springer
The presence of carbon-chain molecules in the interstellar medium (ISM) has been known
since the early 1970s and> 130 such species have been identified to date, making up∼ …