Synthesis of endohedral fullerenes by molecular surgery

S Bloodworth, RJ Whitby - Communications Chemistry, 2022 - nature.com
Encapsulation of atoms or small molecules inside fullerenes provides a unique opportunity
for study of the confined species in the isolated cavity, and the synthesis of closed C60 or …

[HTML][HTML] Water-solid interfaces probed by high-resolution atomic force microscopy

J Peng, J Guo, R Ma, Y Jiang - Surface Science Reports, 2022 - Elsevier
Water-solid interfaces play important roles across a broad range of scientific and application
fields. In the past decades, atomic force microscopy (AFM) has significantly deepened our …

The dipolar endofullerene HF@C60

A Krachmalnicoff, R Bounds, S Mamone, S Alom… - Nature …, 2016 - nature.com
The cavity inside fullerenes provides a unique environment for the study of isolated atoms
and molecules. We report the encapsulation of hydrogen fluoride inside C60 using …

Water in Fullerenes

Y Hashikawa, Y Murata - Bulletin of the Chemical Society of …, 2023 - academic.oup.com
A water molecule fixed within [60] fullerene is the simplest form of water available in
meatspace. It was first artificially made by us in 2011. Since then, anomalies of water …

Separation and Selective Formation of Fullerene Adducts within an MII8L6 Cage

W Brenner, TK Ronson, JR Nitschke - Journal of the American …, 2017 - ACS Publications
The self-assembly of 4-fold-symmetric porphyrins with FeII or ZnII gave a new cubic MII8L6
cage framework with electron-deficient walls. This cage bound C60-indene or C60 …

Dramatically Enhanced Reactivity of Fullerenes and Tetrazine towards the Inverse‐Electron‐Demand Diels–Alder Reaction inside a Porous Porphyrinic Cage

A Dhamija, A Gunnam, X Yu, H Lee… - Angewandte Chemie …, 2022 - Wiley Online Library
Abstract Inverse‐electron‐demand Diels–Alder reaction (IEDDA) between fullerenes and 1,
2, 4, 5‐tetrazine generally requires harsh conditions and long reaction times due to their …

Observation of cnoidal wave localization in nonlinear topolectric circuits

H Hohmann, T Hofmann, T Helbig, S Imhof… - Physical Review …, 2023 - APS
We observe a localized cnoidal (LCn) state in an electric circuit network. Its formation
derives from the interplay of nonlinearity and the topology inherent to a Su-Schrieffer …

Structural Engineering of Nanocarbons Comprising Graphene Frameworks via High-Temperature Annealing

K Pirabul, ZZ Pan, R Tang, S Sunahiro… - Bulletin of the …, 2023 - academic.oup.com
High-temperature annealing is an effective way to heal the defects of graphene-based
nanocarbons and enhance their crystallinity. However, the thermally induced vibration of the …

Ligand-functionalized and ligand-bridged or organyl-separated chalcogenido metalate-based clusters

Z Wu, M Tallu, G Stuhrmann, S Dehnen - Coordination Chemistry Reviews, 2023 - Elsevier
Chalcogenido metalate-based clusters, comprising cluster cores with directly bonded metal
cations and chalcogenide anions, have been a focus of inorganic and materials research for …

Encapsulation of a Water Molecule inside C60 Fullerene: The Impact of Confinement on Quantum Features

O Carrillo-Bohórquez, Á Valdés… - Journal of Chemical …, 2021 - ACS Publications
We introduce an efficient quantum fully coupled computational scheme within the
multiconfiguration time-dependent Hartree (MCTDH) approach to handle the otherwise …