Engineering heterogeneous catalysis with strong metal–support interactions: characterization, theory and manipulation

T Pu, W Zhang, M Zhu - Angewandte Chemie International …, 2023 - Wiley Online Library
Strong metal–support interactions (SMSI) represent a classic yet fast‐growing area in
catalysis research. The SMSI phenomenon results in the encapsulation and stabilization of …

Renaissance of strong metal–support interactions

M Xu, M Peng, H Tang, W Zhou, B Qiao… - Journal of the American …, 2024 - ACS Publications
Strong metal–support interactions (SMSIs) have emerged as a significant and cutting-edge
area of research in heterogeneous catalysis. They play crucial roles in modifying the …

Generation of oxide surface patches promoting H-spillover in Ru/(TiOx)MnO catalysts enables CO2 reduction to CO

H Kang, L Zhu, S Li, S Yu, Y Niu, B Zhang, W Chu… - Nature Catalysis, 2023 - nature.com
The migration of reducible metal oxides (for example, TiO2) to the surface of metal
nanoparticles can inhibit sintering but has a strong negative impact on the catalytic activity …

Structured catalysts and catalytic processes: transport and reaction perspectives

C Pei, S Chen, D Fu, ZJ Zhao, J Gong - Chemical Reviews, 2024 - ACS Publications
The structure of catalysts determines the performance of catalytic processes. Intrinsically, the
electronic and geometric structures influence the interaction between active species and the …

Metal–support interactions in metal/oxide catalysts and oxide–metal interactions in oxide/metal inverse catalysts

Y Li, Y Zhang, K Qian, W Huang - ACS Catalysis, 2022 - ACS Publications
Solid catalysts usually consist of multicomponents, within which interfacial interactions have
been recognized as a key factor affecting structures and catalytic performance. Metal …

Overturning CO2 Hydrogenation Selectivity with High Activity via Reaction-Induced Strong Metal–Support Interactions

H **n, L Lin, R Li, D Li, T Song, R Mu… - Journal of the …, 2022 - ACS Publications
Encapsulation of metal nanoparticles by support-derived materials known as the classical
strong metal–support interaction (SMSI) often happens upon thermal treatment of supported …

Interfacial compatibility critically controls Ru/TiO2 metal-support interaction modes in CO2 hydrogenation

J Zhou, Z Gao, G **ang, T Zhai, Z Liu, W Zhao… - Nature …, 2022 - nature.com
Supports can widely affect or even dominate the catalytic activity, selectivity, and stability of
metal nanoparticles through various metal-support interactions (MSIs). However, underlying …

Ruthenium-cobalt single atom alloy for CO photo-hydrogenation to liquid fuels at ambient pressures

J Zhao, J Liu, Z Li, K Wang, R Shi, P Wang… - Nature …, 2023 - nature.com
Abstract Photothermal Fischer-Tropsch synthesis represents a promising strategy for
converting carbon monoxide into value-added chemicals. High pressures (2-5 MPa) are …

Structure Sensitivity of Au‐TiO2 Strong Metal–Support Interactions

Y Zhang, JX Liu, K Qian, A Jia, D Li… - Angewandte Chemie …, 2021 - Wiley Online Library
Strong metal–support interactions (SMSI) is an important concept in heterogeneous
catalysis. Herein, we demonstrate that the Au‐TiO2 SMSI of Au/TiO2 catalysts sensitively …

Strong Metal–Support Interaction Boosts Activity, Selectivity, and Stability in Electrosynthesis of H2O2

J Zhang, J Ma, TS Choksi, D Zhou, S Han… - Journal of the …, 2022 - ACS Publications
Noble metals have an irreplaceable role in catalyzing electrochemical reactions. However,
large overpotential and poor long-term stability still prohibit their usage in many reactions …