Simulation and theory of ions at atmospherically relevant aqueous liquid-air interfaces

DJ Tobias, AC Stern, MD Baer, Y Levin… - Annual review of …, 2013 - annualreviews.org
Chemistry occurring at or near the surface of aqueous droplets and thin films in the
atmosphere influences air quality and climate. Molecular dynamics simulations are …

Toward a first-principles framework for predicting collective properties of electrolytes

TT Duignan, SM Kathmann, GK Schenter… - Accounts of Chemical …, 2021 - ACS Publications
Conspectus Given the universal importance of electrolyte solutions, it is natural to expect
that we have a nearly complete understanding of the fundamental properties of these …

Massive generation of metastable bulk nanobubbles in water by external electric fields

MR Ghaani, PG Kusalik, NJ English - Science advances, 2020 - science.org
Nanobubbles (NBs) are nanoscopic gaseous domains than can exist on solid surfaces or in
bulk liquids. They have attracted substantial attention due to their long-time (meta) stability …

Image-charge effects on ion adsorption near aqueous interfaces

CY Son, ZG Wang - … of the National Academy of Sciences, 2021 - National Acad Sciences
Electrostatic interactions near surfaces and interfaces are ubiquitous in many fields of
science. Continuum electrostatics predicts that ions will be attracted to conducting …

Mechanism of ion adsorption to aqueous interfaces: Graphene/water vs. air/water

DL McCaffrey, SC Nguyen, SJ Cox… - Proceedings of the …, 2017 - National Acad Sciences
The adsorption of ions to aqueous interfaces is a phenomenon that profoundly influences
vital processes in many areas of science, including biology, atmospheric chemistry …

The influence of water interfacial potentials on ion hydration in bulk water and near interfaces

TL Beck - Chemical Physics Letters, 2013 - Elsevier
The surface potential at the water liquid–vapor interface is discussed in relation to
experimental determinations of bulk absolute ion hydration free energies. It is shown that …

[PDF][PDF] Charge asymmetry at aqueous hydrophobic interfaces and hydration shells.

R Scheu, BM Rankin, Y Chen, KC Jena… - Angewandte Chemie …, 2014 - epfl.ch
The solvation of ions in a dielectric continuum is symmetric with respect to the sign of the
ionic charge. Yet, many phenomena show indirect evidence that water may have a …

Does the Sign of Charge Affect the Surface Affinity of Simple Ions?

G Hantal, M Klíma, L McFegan, J Kolafa… - The Journal of …, 2023 - ACS Publications
The role the charge sign of simple ions plays in determining their surface affinity in aqueous
solutions is investigated by computer simulation methods. For this purpose, the free surface …

Optical label-free and model-free probe of the surface potential of nanoscale and microscopic objects in aqueous solution

C Lütgebaucks, G Gonella, S Roke - Physical Review B, 2016 - APS
The electrostatic environment of aqueous systems is an essential ingredient for the function
of any living system. To understand the electrostatic properties and their molecular …

Two sides of the acid–base story

RJ Saykally - Nature chemistry, 2013 - nature.com
The ability of the water surface to donate or accept protons critically influences vital
processes in chemistry and biology, but intense disagreement persists regarding this …