Multiscale CO2 Electrocatalysis to C2+ Products: Reaction Mechanisms, Catalyst Design, and Device Fabrication

T Yan, X Chen, L Kumari, J Lin, M Li, Q Fan… - Chemical …, 2023 - ACS Publications
Electrosynthesis of value-added chemicals, directly from CO2, could foster achievement of
carbon neutral through an alternative electrical approach to the energy-intensive …

Surface engineering for stable electrocatalysis

VH Do, JM Lee - Chemical Society Reviews, 2024 - pubs.rsc.org
In recent decades, significant progress has been achieved in rational developments of
electrocatalysts through constructing novel atomistic structures and modulating catalytic …

Atomic-scale surface restructuring of copper electrodes under CO2 electroreduction conditions

R Amirbeigiarab, J Tian, A Herzog, C Qiu… - Nature Catalysis, 2023 - nature.com
Potentiodynamic methods that induce structural changes in Cu catalysts for the
electrochemical reduction of CO2 (CO2RR) have been identified as a promising strategy for …

In Situ Infrared Spectroscopic Evidence of Enhanced Electrochemical CO2 Reduction and C–C Coupling on Oxide-Derived Copper

EP Delmo, Y Wang, Y Song, S Zhu… - Journal of the …, 2024 - ACS Publications
The reaction mechanism of CO2 electroreduction on oxide-derived copper has not yet been
unraveled even though high C2+ Faradaic efficiencies are commonly observed on these …

Cascade electrocatalysis via AgCu single-atom alloy and Ag nanoparticles in CO2 electroreduction toward multicarbon products

C Du, JP Mills, AG Yohannes, W Wei, L Wang… - Nature …, 2023 - nature.com
Electrocatalytic CO2 reduction into value-added multicarbon products offers a means to
close the anthropogenic carbon cycle using renewable electricity. However, the …

Solution-based Cu+ transient species mediate the reconstruction of copper electrocatalysts for CO2 reduction

J Vavra, GPL Ramona, F Dattila, A Kormányos… - Nature Catalysis, 2024 - nature.com
Understanding metal surface reconstruction is of the utmost importance in electrocatalysis,
as this phenomenon directly affects the nature of available active sites. However, its dynamic …

Experimental evidence of distinct sites for CO2-to-CO and CO conversion on Cu in the electrochemical CO2 reduction reaction

W Gao, Y Xu, L Fu, X Chang, B Xu - Nature Catalysis, 2023 - nature.com
The electrochemical CO2 reduction reaction on Cu is widely believed to occur via two
consecutive and orthogonal reaction steps, that is, CO2-to-CO and CO-to-C2+, on the same …

In situ X-ray spectroscopies beyond conventional X-ray absorption spectroscopy on deciphering dynamic configuration of electrocatalysts

J Wang, CS Hsu, TS Wu, TS Chan, NT Suen… - Nature …, 2023 - nature.com
Realizing viable electrocatalytic processes for energy conversion/storage strongly relies on
an atomic-level understanding of dynamic configurations on catalyst-electrolyte interface. X …

Electrochemical CO2 reduction (CO2RR) to multi-carbon products over copper-based catalysts

AR Woldu, Z Huang, P Zhao, L Hu, D Astruc - Coordination Chemistry …, 2022 - Elsevier
Copper has been recognized as the only heterogeneous catalyst leading to the formation of
various products of hydrocarbons and oxygenates, such as ethanol and ethylene, from the …

Spatially and temporally understanding dynamic solid–electrolyte interfaces in carbon dioxide electroreduction

J Wang, HY Tan, MY Qi, JY Li, ZR Tang… - Chemical Society …, 2023 - pubs.rsc.org
The ubiquity of solid–liquid interfaces in nature and the significant role of their atomic-scale
structure in determining interfacial properties have led to intensive research. Particularly in …