The design of synthetic routes by retrosynthetic logic is decisively influenced by the
transformations available. Transition‐metal‐catalyzed C− H activation has emerged as a …

Transition metal-mediated C–H bond activation and functionalization represent one of the
most straightforward and powerful tools in modern organic synthetic chemistry. Bi (hetero) …

Azines, which are six-membered aromatic compounds containing one or more nitrogen
atoms, serve as ubiquitous structural cores of aromatic species with important applications in …

C− C bond formation is a fundamental transformation in organic synthesis. The development
of new synthetic methodology could be considered as a way of pursuing a novel method for …

In recent years, transition metal‐catalyzed direct (hetero) arylation reactions of heteroarenes
with (hetero) aryl halides and pseudohalides have received significant attention as eco …

Rh (III)-catalyzed C–H activation assisted by an oxidizing directing group has evolved to a
mild and redox-economic strategy for the construction of heterocycles. Despite the success …

Reported herein is the metal-catalyzed regioselective C–H functionalization of quinoline N-
oxides at the 8-position: direct iodination and amidation were developed using rhodium and …

Quinoline is an important scaffold in many natural products, biologically active compounds,
and functional materials. The C–H functionalization of quinoline scaffolds by transition metal …

Quinoxaline has become a subject of extensive research due to its emergence as an
important chemical moiety, demonstrating a wide range of physicochemical and biological …

This article describes detailed mechanistic studies focused on elucidating the impact of
pyridine ligands on the Pd-catalyzed C–H acetoxylation of benzene. Three different …