Catalytic carbophilic activation: catalysis by platinum and gold π acids

A Fürstner, PW Davies - Angewandte Chemie International …, 2007 - Wiley Online Library
The ability of platinum and gold catalysts to effect powerful atom‐economic transformations
has led to a marked increase in their utilization. The quite remarkable correlation of their …

Alternative synthetic methods through new developments in catalysis by gold

A Arcadi - Chemical Reviews, 2008 - ACS Publications
Synthetic chemists are constantly challenged to consider more environmentally benign
methods for generation of the desired target molecules. 1 Recently, there has been an …

Transition-metal mediated carbon–sulfur bond activation and transformations

L Wang, W He, Z Yu - Chemical Society Reviews, 2013 - pubs.rsc.org
C–S bond activation, cleavage and transformations by means of transition metal compounds
have recently become more and more important in the petroleum industry and synthetic …

Katalytische carbophile Aktivierung: Platin‐und Gold‐π‐Säuren als Katalysatoren

A Fürstner, PW Davies - Angewandte Chemie, 2007 - Wiley Online Library
Platin‐und Goldkatalysatoren gewinnen aufgrund ihrer hohen Effizienz und erstaunlichen
Vielfalt für atomökonomische Umsetzungen rasch an Bedeutung. Dabei erlaubt es die …

Gold-catalyzed intramolecular regio-and enantioselective cycloisomerization of 1, 1-bis (indolyl)-5-alkynes.

L Huang, HB Yang, DH Zhang… - Angewandte …, 2013 - search.ebscohost.com
Bis (indole) alkaloids analogues were prepared under mild conditions and in high yields
through a gold‐catalyzed cycloisomerization of 1, 1‐bis (indolyl)‐5‐alkynes (see scheme) …

A Highly Efficient Friedel–Crafts Reaction of 3‐Hydroxyoxindoles and Aromatic Compounds to 3, 3‐Diaryl and 3‐Alkyl‐3‐aryloxindoles Catalyzed by Hg (ClO4) 2⋅ 3 …

F Zhou, ZY Cao, J Zhang, HB Yang… - Chemistry–An Asian …, 2012 - Wiley Online Library
We report a highly efficient Friedel–Crafts reaction of 3‐alkyl or 3‐aryl 3‐hydroxyoxindoles
with a variety of aromatic and heteroaromatic compounds to unsymmetrical 3, 3 …

Synthesis of 3-oxooxa-and 3-oxoazacycloalk-4-enes by ring-closing metathesis. Application to the synthesis of an inhibitor of cathepsin K

C Taillier, T Hameury, V Bellosta, J Cossy - Tetrahedron, 2007 - Elsevier
Synthesis of 3-oxooxa- and 3-oxoazacycloalk-4-enes by ring-closing metathesis. Application
to the synthesis of an inhibitor of cathepsin K - ScienceDirect Skip to main contentSkip to …

Calcium-catalyzed bis-hydrothiolation of unactivated alkynes providing dithioacetals

M Hut'ka, T Tsubogo, S Kobayashi - Organometallics, 2014 - ACS Publications
Bis-hydrothiolation of alkynes providing anti-Markovnikov dithioacetals is reported. Lewis-
acidic Ca (OSO2C4F9) 2 (Ca (ONf) 2) was synthesized for the first time and was shown to be …

Preparation of Z-α,β-Unsaturated Diazoketones from Aldehydes. Application in the Construction of Substituted Dihydropyridin-3-ones

IG Rosset, ACB Burtoloso - The Journal of Organic Chemistry, 2013 - ACS Publications
The stereoselective preparation of α, β-unsaturated diazoketones with Z geometry is
described from aldehydes and a new olefination reagent. When prepared from amino …

A highly efficient Hg (OTf) 2-mediated Sakurai–Hosomi allylation of N-tert-butyloxycarbonylamino sulfones, aldehydes, fluoroalkyl ketones and α, β-unsaturated …

Y Gong, ZY Cao, YB Shi, F Zhou, Y Zhou… - Organic Chemistry …, 2019 - pubs.rsc.org
It is reported that cheap and easily available Hg (OTf) 2 can efficiently mediate the Sakurai–
Hosomi reaction of N-tert-butyloxycarbonyl (Boc) amino sulfones, aldehydes, and α …