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Excimer and exciplex formation in gold (I) complexes preconditioned by aurophilic interactions
H Schmidbaur… - Angewandte Chemie …, 2020 - Wiley Online Library
Excimers and exciplexes are defined as assemblies of atoms or molecules A/A′ where
interatomic/intermolecular bonding appears only in excited states such as [A2]*(for …
interatomic/intermolecular bonding appears only in excited states such as [A2]*(for …
Tracking ultrafast structural dynamics by time-domain Raman spectroscopy
H Kuramochi, T Tahara - Journal of the American Chemical …, 2021 - ACS Publications
In traditional Raman spectroscopy, narrow-band light is irradiated on a sample, and its
inelastic scattering, ie, Raman scattering, is detected. The energy difference between the …
inelastic scattering, ie, Raman scattering, is detected. The energy difference between the …
Ultrafast X-ray crystallography and liquidography
Time-resolved X-ray diffraction provides direct information on three-dimensional structures
of reacting molecules and thus can be used to elucidate structural dynamics of chemical and …
of reacting molecules and thus can be used to elucidate structural dynamics of chemical and …
Photoinduced dynamics in solution is governed by mutual solute–solvent interactions, which
give rise to phenomena like solvatochromism, the Stokes shift, dual fluorescence, or charge …
give rise to phenomena like solvatochromism, the Stokes shift, dual fluorescence, or charge …
Tracking photoinduced Au–Au bond formation through transient terahertz vibrations observed by femtosecond time-domain Raman spectroscopy
H Kuramochi, S Takeuchi, M Iwamura… - Journal of the …, 2019 - ACS Publications
Real-time observation of chemical bond formation and subsequent nuclear rearrangements
is an ultimate goal of chemical science. Yet, such attempts have been hampered by the …
is an ultimate goal of chemical science. Yet, such attempts have been hampered by the …
Structural dynamics of the heme pocket and intersubunit coupling in the dimeric hemoglobin from Scapharca inaequivalvis
Cooperativity is essential for the proper functioning of numerous proteins by allosteric
interactions. Hemoglobin from Scapharca inaequivalvis (HbI) is a homodimeric protein that …
interactions. Hemoglobin from Scapharca inaequivalvis (HbI) is a homodimeric protein that …
[HTML][HTML] Projection to extract the perpendicular component (PEPC) method for extracting kinetics from time-resolved data
Time-resolved x-ray liquidography (TRXL) is a potent method for investigating the structural
dynamics of chemical and biological reactions in the liquid phase. It has enabled the …
dynamics of chemical and biological reactions in the liquid phase. It has enabled the …
The chemical bond and s–d hybridization in coinage metal (I) cyanides
We present a four-component relativistic density functional theory study of the chemical
bond and s–d hybridization in the group 11 cyanides M–CN (M= Cu, Ag, and Au). The …
bond and s–d hybridization in the group 11 cyanides M–CN (M= Cu, Ag, and Au). The …
Optical Kerr effect of liquid acetonitrile probed by femtosecond time-resolved x-ray liquidography
Optical Kerr effect (OKE) spectroscopy is a method that measures the time-dependent
change of the birefringence induced by an optical laser pulse using another optical laser …
change of the birefringence induced by an optical laser pulse using another optical laser …
[HTML][HTML] A versatile experimental system for tracking ultrafast chemical reactions with X-ray free-electron lasers
T Katayama, S Nozawa, Y Umena, SH Lee… - Structural …, 2019 - pubs.aip.org
An experimental system, SPINETT (SACLA Pump-probe INstrumEnt for Tracking Transient
dynamics), dedicated for ultrafast pump-probe experiments using X-ray free-electron lasers …
dynamics), dedicated for ultrafast pump-probe experiments using X-ray free-electron lasers …