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Recent advances of Cp* Ir complexes for transfer hydrogenation: focus on formic acid/formate as hydrogen donors
YF Wei, Y Liang, R Luo, L Ouyang - Organic & Biomolecular Chemistry, 2023 - pubs.rsc.org
Transfer hydrogenation reactions offer synthetically powerful strategies to deliver various
hydrogenated compounds with the advantages of efficiency, atom economy, and …
hydrogenated compounds with the advantages of efficiency, atom economy, and …
[HTML][HTML] The acquisition of primary amines from alcohols through reductive amination over heterogeneous catalysts
H Huang, Y Wei, Y Cheng, S **ao, M Chen, Z Wei - Catalysts, 2023 - mdpi.com
The synthesis of primary amines via the reductive amination of alcohols involves a hydrogen-
borrowing or hydrogen-transfer mechanism, which consists of three main steps: alcohol …
borrowing or hydrogen-transfer mechanism, which consists of three main steps: alcohol …
Enantioselective total synthesis of (−)-himalensine a via a palladium and 4-hydroxyproline co-catalyzed desymmetrization of vinyl-bromide-tethered cyclohexanones
Herein, we describe the convergent enantioselective total synthesis of himalensine A in 18
steps, enabled by a highly enantio-and diastereoselective construction of the morphan core …
steps, enabled by a highly enantio-and diastereoselective construction of the morphan core …
Reductive aminomethylation using ammonium formate and methanol as N1 and C1 source: Direct synthesis of mono-and di-methylated amines
An Ir (III) complex catalyzed single and dual reductive amination followed by N-methylation
of aldehydes and ketones to synthesize N, N-dimethyl as well as N-methyl tertiary amines …
of aldehydes and ketones to synthesize N, N-dimethyl as well as N-methyl tertiary amines …
Mechanistic Investigations on Cp*CoIII-Catalyzed Quinoline Transfer Hydrogenation with Formic Acid
The mechanism of the quinoline transfer hydrogenation (TH) by aqueous HCOOH under the
action of [Cp* Co (quinNH2) I]+(A*; quinNH2= 8-aminoquinoline) has been investigated by a …
action of [Cp* Co (quinNH2) I]+(A*; quinNH2= 8-aminoquinoline) has been investigated by a …
Synthesis of Chiral Primary Amines via Enantioselective Reductive Amination: From Academia to Industry
Chiral primary amines widely exist in drugs and are exceptionally important subunits or
synthons in the syntheses of chiral secondary and tertiary amines of medicinal interest …
synthons in the syntheses of chiral secondary and tertiary amines of medicinal interest …
A brief review: advancement in the synthesis of amine through the Leuckart reaction
This review presents a summary of reactions that take place during the “Leuckart-type
reaction”. The significance of, as well as recent advancements in, the synthesis of amines …
reaction”. The significance of, as well as recent advancements in, the synthesis of amines …
ZIF‐67 Derived Co/NC Nanoparticles Enable Catalytic Leuckart‐type Reductive Amination of Bio‐based Carbonyls to N‐Formyl Compounds
It is of great significance to develop non‐precious metal catalysts with excellent catalytic
activity, stability, and acid resistance for biomass valorization. Herein, catalytic amination of …
activity, stability, and acid resistance for biomass valorization. Herein, catalytic amination of …
Direct reductive amination of ketones with ammonium salt catalysed by Cp* Ir (iii) complexes bearing an amidato ligand
Z Dai, YM Pan, SG Wang, X Zhang… - Organic & Biomolecular …, 2021 - pubs.rsc.org
A series of half-sandwich Ir (III) complexes 1–6 bearing an amidato bidentate ligand were
conveniently synthesized and applied to the catalytic Leuckart–Wallach reaction to produce …
conveniently synthesized and applied to the catalytic Leuckart–Wallach reaction to produce …
[HTML][HTML] Highly efficient synthesis of chiral β-amino phosphine derivatives via direct asymmetric reductive amination with ammonium salts and H2
Y Liu, L Wang, Y Li, B Ma, GQ Chen, X Zhang - Green Synthesis and …, 2022 - Elsevier
A highly efficient and enantioselective method for the asymmetric reductive amination of β-
keto phosphine derivatives was disclosed, and the corresponding β-amino phosphine …
keto phosphine derivatives was disclosed, and the corresponding β-amino phosphine …