Characterization of Intermediate Oxidation States in CO2 Activation

LG Dodson, MC Thompson… - Annual review of physical …, 2018 - annualreviews.org
Redox chemistry during the activation of carbon dioxide involves changing the charge state
in a CO2 molecular unit. However, such changes are usually not well described by integer …

Photoelectron imaging of negative ions

A Sanov, R Mabbs - International Reviews in Physical Chemistry, 2008 - Taylor & Francis
This article provides an overview of some of the recent advances in the rapidly growing field
of negative-ion photoelectron imaging spectroscopy. Setting the work that spans several …

sp2/sp3 Framework from Diamond Nanocrystals: A Key Bridge of Carbonaceous Structure to Carbocatalysis

X Duan, W Tian, H Zhang, H Sun, Z Ao, Z Shao… - ACS …, 2019 - ACS Publications
Diamond nanocrystals in robust sp3 hybridization are appealing carbonaceous materials in
the material community, whose structure can be transformed into unique sp2/sp3 …

Selective Photoelectrochemical Reduction of Aqueous CO2 to CO by Solvated Electrons

L Zhang, D Zhu, GM Nathanson… - Angewandte …, 2014 - Wiley Online Library
Reduction of CO2 by direct one‐electron activation is extraordinarily difficult because of the−
1.9 V reduction potential of CO2. Demonstrated herein is reduction of aqueous CO2 to CO …

The interaction of negative charge with carbon dioxide–insight into solvation, speciation and reductive activation from cluster studies

JM Weber - International Reviews in Physical Chemistry, 2014 - Taylor & Francis
The interaction of CO2 with negative charge is of high importance in many natural and
industrial processes, since reductive activation is one of the most common and convenient …

Note: A novel dual-channel time-of-flight mass spectrometer for photoelectron imaging spectroscopy

Z Qin, X Wu, Z Tang - Review of Scientific Instruments, 2013 - pubs.aip.org
A novel dual-channel time-of-flight mass spectrometer (D-TOFMS) has been designed to
select anions in the photoelectron imaging measurements. In this instrument, the radiation …

Thermochemistry from ion–molecule reactions of hydrated ions in the gas phase: a new variant of nanocalorimetry reveals product energy partitioning

RF Höckendorf, OP Balaj, C van der Linde… - Physical Chemistry …, 2010 - pubs.rsc.org
A new variant of nanocalorimetry is proposed for the thermochemical analysis of ion–
molecule reactions of hydrated ions in the gas phase. The average number of water …

Photodetachment anisotropy for mixed sp states: 8/3 and other fractions

A Sanov, ER Grumbling, DJ Goebbert… - The Journal of chemical …, 2013 - pubs.aip.org
AAAS Science and Technology Policy Fellow placed at the National Science Foundation
(2012-2013). Any opinions, findings, and conclusions or recommendations expressed in this …

Spectroscopy of ethylenedione

AR Dixon, T Xue, A Sanov - Angewandte Chemie International …, 2015 - Wiley Online Library
The long sought‐after, intrinsically short‐lived molecule ethylenedione (OCCO) was
observed and investigated by anion photoelectron spectroscopy. The adiabatic electron …

Photoelectron spectroscopic study of the oxyallyl diradical

T Ichino, SM Villano, AJ Gianola… - The Journal of …, 2011 - ACS Publications
The photoelectron spectrum of the oxyallyl (OXA) radical anion has been measured. The
radical anion has been generated in the reaction of the atomic oxygen radical anion (O•−) …