Theoretical advances in polariton chemistry and molecular cavity quantum electrodynamics

A Mandal, MAD Taylor, BM Weight… - Chemical …, 2023 - ACS Publications
When molecules are coupled to an optical cavity, new light–matter hybrid states, so-called
polaritons, are formed due to quantum light–matter interactions. With the experimental …

Manipulating matter by strong coupling to vacuum fields

FJ Garcia-Vidal, C Ciuti, TW Ebbesen - Science, 2021 - science.org
BACKGROUND One of the most important phenomena in cavity quantum electrodynamics
(cQED) is the so-called strong coupling regime, which appears when the interaction …

Understanding polaritonic chemistry from ab initio quantum electrodynamics

M Ruggenthaler, D Sidler, A Rubio - Chemical Reviews, 2023 - ACS Publications
In this review, we present the theoretical foundations and first-principles frameworks to
describe quantum matter within quantum electrodynamics (QED) in the low-energy regime …

Ultrastrong coupling between light and matter

A Frisk Kockum, A Miranowicz, S De Liberato… - Nature Reviews …, 2019 - nature.com
Ultrastrong coupling between light and matter has, in the past decade, transitioned from a
theoretical idea to an experimental reality. It is a new regime of quantum light–matter …

Cavity frequency-dependent theory for vibrational polariton chemistry

X Li, A Mandal, P Huo - Nature communications, 2021 - nature.com
Recent experiments demonstrate the control of chemical reactivities by coupling molecules
inside an optical microcavity. In contrast, transition state theory predicts no change of the …

[LIBRO][B] The Jaynes–Cummings model and its descendants: modern research directions

J Larson, T Mavrogordatos - 2021 - iopscience.iop.org
The Jaynes–Cummings Model (JCM) has recently been receiving increased attention as
one of the simplest, yet intricately nonlinear, models of quantum physics. Emphasising the …

Light–matter interactions with photonic quasiparticles

N Rivera, I Kaminer - Nature Reviews Physics, 2020 - nature.com
Interactions between light and matter play an instrumental role in spectroscopy, sensing,
quantum information processing and lasers. In most of these applications, light is considered …

Introduction to the Dicke Model: From Equilibrium to Nonequilibrium, and Vice Versa

P Kirton, MM Roses, J Keeling… - Advanced Quantum …, 2019 - Wiley Online Library
The Dicke model describes the coupling between a quantized cavity field and a large
ensemble of two‐level atoms. When the number of atoms tends to infinity, this model can …

Relevance of the quadratic diamagnetic and self-polarization terms in cavity quantum electrodynamics

C Schäfer, M Ruggenthaler, V Rokaj, A Rubio - ACS photonics, 2020 - ACS Publications
Experiments at the interface of quantum optics and chemistry have revealed that strong
coupling between light and matter can substantially modify the chemical and physical …

Observation of a superradiant phase transition with emergent cat states

RH Zheng, W Ning, YH Chen, JH Lü, LT Shen, K Xu… - Physical Review Letters, 2023 - APS
Superradiant phase transitions (SPTs) are important for understanding light-matter
interactions at the quantum level, and play a central role in criticality-enhanced quantum …